A simplified method of preparing phosphoric acid for stable isotope analyses of carbonates

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Abstract

In order to produce CO2 for stable isotope analyses (delta(18)O and delta(13)C), carbonate samples are commonly digested in phosphoric acid. The acid recipe here presented is based on phase shifting crystalline orthophosphoric acid of pro-analysis quality to a liquid state through heating, followed by pre-vacuum treatment during a start-up procedure before mass analyses for common acid bath preparation, or adding a small amount of phosphoric pentoxide for single drop equipments, respectively. This methodology results in a final acid concentration of 104%.

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  • Geology
Original languageEnglish
Pages (from-to)3086-3088
JournalRapid Communications in Mass Spectrometry
Volume19
Issue number21
StatePublished - 2005
Peer-reviewedYes