Ambient pressure phase transitions over Ir(1 1 1): at the onset of CO oxidation
Research output: Contribution to journal › Article
In this study we report on the adsorbate structures on an Ir(1 1 1) surface during the phase transition from the inactive to the active state during CO oxidation. The CO oxidation over Pt(1 1 1) is used as a reference case. Where Pt(1 1 1) either is inactive and CO covered or active and O covered, Ir(1 1 1) exhibits a transition state with co-existing chemisorbed O and CO. The observed structural differences are explained in terms of DFT-calculated adsorption energies. For Pt(1 1 1) the repulsive CO–O interaction makes co-existing chemisorbed CO and O unfavourable, while for Ir(1 1 1) the stronger O and CO adsorption allows for overcoming the repulsive interaction. At the onset of CO oxidation over Ir(1 1 1), a CO structure containing defects forms, which enables O2 to dissociatively adsorb on the Ir(1 1 1) surface, thus enabling the CO oxidation reaction. At the mass transfer limit, the Ir(1 1 1) surface is covered by a chemisorbed O structure with defects; hence, the active surface is predominately chemisorbed O covered at a total pressure of 0.5 mbar and no oxide formation is observed.
|Research areas and keywords||
Subject classification (UKÄ) – MANDATORY
|Journal||Journal of Physics: Condensed Matter|
|State||Published - 2017 Oct 5|
Related research output
Niclas Johansson 2017 Oct Lund: Lund University, Faculty of Science, Department of Physics. 216 p.
Research output: Thesis › Doctoral Thesis (compilation)