[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-kappa P-3,C-1,P '](trifluoroacetato)palladium(II)

Magnus Johnson; Mario Cetina; Kari Rissanen; Ola Wendt

doi:10.1107/S1600536810017861

[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-kappa P-3,C-1,P '](trifluoroacetato)palladium(II)

Magnus Johnson, Mario Cetina, Kari Rissanen, Ola Wendt

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

The Pd-II atom in the title compound, [Pd(C2F3O2)(C24H43P2)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intramolecular C-H center dot center dot center dot O hydrogen bonds occur. The crystal packing reveals one weak intermolecular C-H center dot center dot center dot O hydrogen bond, which self-assembles the molecules into infinite chains parallel to the b axis.

Original language	English
Pages (from-to)	M675-U737
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
DOIs	https://doi.org/10.1107/S1600536810017861
Publication status	Published - 2010

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

Subject classification (UKÄ)

Organic Chemistry

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10.1107/S1600536810017861

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title = "[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-kappa P-3,C-1,P '](trifluoroacetato)palladium(II)",

abstract = "The Pd-II atom in the title compound, [Pd(C2F3O2)(C24H43P2)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intramolecular C-H center dot center dot center dot O hydrogen bonds occur. The crystal packing reveals one weak intermolecular C-H center dot center dot center dot O hydrogen bond, which self-assembles the molecules into infinite chains parallel to the b axis.",

author = "Magnus Johnson and Mario Cetina and Kari Rissanen and Ola Wendt",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)",

year = "2010",

doi = "10.1107/S1600536810017861",

language = "English",

volume = "66",

pages = "M675--U737",

journal = "Acta Crystallographica Section E: Structure Reports Online",

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publisher = "International Union of Crystallography",

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T1 - [2,6-Bis(di-tert-butylphosphinomethyl)phenyl-kappa P-3,C-1,P '](trifluoroacetato)palladium(II)

AU - Johnson, Magnus

AU - Cetina, Mario

AU - Rissanen, Kari

AU - Wendt, Ola

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

PY - 2010

Y1 - 2010

N2 - The Pd-II atom in the title compound, [Pd(C2F3O2)(C24H43P2)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intramolecular C-H center dot center dot center dot O hydrogen bonds occur. The crystal packing reveals one weak intermolecular C-H center dot center dot center dot O hydrogen bond, which self-assembles the molecules into infinite chains parallel to the b axis.

AB - The Pd-II atom in the title compound, [Pd(C2F3O2)(C24H43P2)], adopts a distorted square-planar geometry with the P atoms in a trans arrangement, forming two five-membered chelate rings. Four intramolecular C-H center dot center dot center dot O hydrogen bonds occur. The crystal packing reveals one weak intermolecular C-H center dot center dot center dot O hydrogen bond, which self-assembles the molecules into infinite chains parallel to the b axis.

U2 - 10.1107/S1600536810017861

DO - 10.1107/S1600536810017861

M3 - Article

C2 - 21579315

SN - 1600-5368

VL - 66

SP - M675-U737

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

[2,6-Bis(di-tert-butylphosphinomethyl)phenyl-kappa P-3,C-1,P '](trifluoroacetato)palladium(II)

Abstract

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