A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Martin Jarenmark; Elena A. Turitsyna; Matti Haukka; Albert A. Shteinman; Ebbe Nordlander

doi:10.1039/c0nj00293c

A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Martin Jarenmark, Elena A. Turitsyna, Matti Haukka, Albert A. Shteinman, Ebbe Nordlander

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

Original language	English
Pages (from-to)	2118-2121
Journal	New Journal of Chemistry
Volume	34
Issue number	10
DOIs	https://doi.org/10.1039/c0nj00293c
Publication status	Published - 2010

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Access to Document

10.1039/c0nj00293c

Cite this

@article{8ea962e6b0384d3686eb5d9a4c57c10d,

title = "A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide",

abstract = "Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.",

author = "Martin Jarenmark and Turitsyna, {Elena A.} and Matti Haukka and Shteinman, {Albert A.} and Ebbe Nordlander",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2010",

doi = "10.1039/c0nj00293c",

language = "English",

volume = "34",

pages = "2118--2121",

journal = "New Journal of Chemistry",

issn = "1369-9261",

publisher = "Royal Society of Chemistry",

number = "10",

}

TY - JOUR

T1 - A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

AU - Jarenmark, Martin

AU - Turitsyna, Elena A.

AU - Haukka, Matti

AU - Shteinman, Albert A.

AU - Nordlander, Ebbe

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2010

Y1 - 2010

N2 - Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

AB - Reaction of the ligand 2-(N-isopropyl-N-{(2-pyridyl)methyl}aminomethyl)- 6-(N-(carboxymethyl)-N-((2-pyridyl)-methyl) aminomethyl)- 4-methylphenol (H2IPCPMP) with two equivalents of Fe(ClO4)(2) and two equivalents of sodium pivalate in air leads to the formation of the mu-oxido, mu-carboxylato-bridged diiron complex [{Fe(H-IPCPMP)}(2)(mu-O)(Piv)]ClO4 (1) (Piv = pivalate). Complex 1 is capable of catalysing the oxidation of cyclohexane or 1,2-cis-dimethylcyclohexane by hydrogen peroxide, leading to the formation of the corresponding cyclohexanone and cyclohexanol, as well as a small amount of cyclohexyl hydroperoxide.

U2 - 10.1039/c0nj00293c

DO - 10.1039/c0nj00293c

M3 - Article

SN - 1369-9261

VL - 34

SP - 2118

EP - 2121

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 10

ER -

A monocarboxylate-bridged diiron(III) mu-oxido complex that catalyzes alkane oxidation by hydrogen peroxide

Abstract

Bibliographical note

Subject classification (UKÄ)

Access to Document

Fingerprint

Cite this