A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis

Sang Hyun Pyo; Ji Hoon Park; Vanessa Srebny; Rajni Hatti-Kaul

doi:10.1039/d0gc01454k

A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis

Sang Hyun Pyo, Ji Hoon Park, Vanessa Srebny, Rajni Hatti-Kaul

Research output: Contribution to journal › Article › peer-review

Abstract

A green route for the production of 6-carbon polymer building blocks 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone from 1,6-hexanediol, a hydrogenation product of biobased 5-hydroxymethylfurfural is reported. Gluconobacter oxydans oxidized 1,6-hexanediol completely to adipic acid, and selectively at pH 6-7 to 6-hydroxyhexanoic acid, which was converted to ϵ-caprolactone by catalytic cyclization. This journal is

Original language	English
Pages (from-to)	4450-4455
Number of pages	6
Journal	Green Chemistry
Volume	22
Issue number	14
DOIs	https://doi.org/10.1039/d0gc01454k
Publication status	Published - 2020

Subject classification (UKÄ)

Biocatalysis and Enzyme Technology

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10.1039/d0gc01454k

STEPS: STEPS – Sustainable Plastics and Transition Pathways, Phase 1
Generosi, J. (Project coordinator), Hatti-Kaul, R. (PI), Pyo, S.-H. (Researcher), Zhang, B. (PI), Turner, C. (Researcher), Rodriguez Meizoso, I. (Researcher), Wallberg, O. (Researcher), Hulteberg, C. (CoI), Diegel, O. (Researcher), Ristinmaa, M. (Researcher), Nilsson, L. J. (PI), Palm, E. (Research student), Ericsson, K. (Researcher), Hansen, T. (CoI), Klintman, M. (Researcher), Stripple, J. (Researcher), Bauer, F. (Researcher), Madsen, S. (PI), Jannasch, P. (Researcher), Egan, N. (Project communication officer), Nielsen, T. (Researcher), Holmberg, K. (Research assistant), Svantesson, A. (Research assistant), Hall, S. (Researcher), Mahmoud, S. (Researcher), Englund Örn, O. (Research student), Mankar, S. (Research student), Warlin, N. (Research student), Valsange, N. (Research student), Sanku, M. (Research student), Hasselbalch, J. (Researcher), Sjölin, M. (Research student), Hansen, T. (Researcher), Chen, L. (Research student), Nordin, A. (Researcher), Engqvist, J. (Research student), Garcia Gonzalez, N. (Researcher), Newson, W. R. (Researcher), Johansson, E. (Researcher), Kuktaite, R. (Researcher), Muneer, F. (Researcher), Nilsson , E. (Researcher), Guo, Z. (Researcher), Ahlqvist, J. (Administrator) & Peric, S. (Administrator)
MISTRA, Swedish foundation for strategic environmental research
2016/09/01 → 2020/08/31
Project: Research

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AU - Hatti-Kaul, Rajni

PY - 2020

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DO - 10.1039/d0gc01454k

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A sustainable synthetic route for biobased 6-hydroxyhexanoic acid, adipic acid and ϵ-caprolactone by integrating bio- And chemical catalysis

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STEPS: STEPS – Sustainable Plastics and Transition Pathways, Phase 1

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