A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity

Algirdas Neniškis; Dovilė Račkauskaitė; Qixun Shi; Aiden J. Robertson; Andrew Marsh; Artūras Ulčinas; Ramūnas Valiokas; Steven P. Brown; Kenneth Wärnmark; Edvinas Orentas

doi:10.1002/chem.201803701

A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity

Algirdas Neniškis, Dovilė Račkauskaitė, Qixun Shi, Aiden J. Robertson, Andrew Marsh, Artūras Ulčinas, Ramūnas Valiokas, Steven P. Brown, Kenneth Wärnmark, Edvinas Orentas

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by ¹H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.

Original language	English
Pages (from-to)	14028-14033
Number of pages	6
Journal	Chemistry - A European Journal
Volume	24
Issue number	53
DOIs	https://doi.org/10.1002/chem.201803701
Publication status	Published - 2018 Sept 20

Subject classification (UKÄ)

Polymer Chemistry

Free keywords

fullerenes
hydrogen-bond
molecular tubes
self-assembly
solid-state NMR

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10.1002/chem.201803701

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title = "A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity",

abstract = "A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.",

keywords = "fullerenes, hydrogen-bond, molecular tubes, self-assembly, solid-state NMR",

author = "Algirdas Neni{\v s}kis and Dovilė Ra{\v c}kauskaitė and Qixun Shi and Robertson, {Aiden J.} and Andrew Marsh and Artūras Ul{\v c}inas and Ramūnas Valiokas and Brown, {Steven P.} and Kenneth W{\"a}rnmark and Edvinas Orentas",

year = "2018",

month = sep,

day = "20",

doi = "10.1002/chem.201803701",

language = "English",

volume = "24",

pages = "14028--14033",

journal = "Chemistry - A European Journal",

issn = "0947-6539",

publisher = "Wiley-Blackwell",

number = "53",

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TY - JOUR

T1 - A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity

AU - Neniškis, Algirdas

AU - Račkauskaitė, Dovilė

AU - Shi, Qixun

AU - Robertson, Aiden J.

AU - Marsh, Andrew

AU - Ulčinas, Artūras

AU - Valiokas, Ramūnas

AU - Brown, Steven P.

AU - Wärnmark, Kenneth

AU - Orentas, Edvinas

PY - 2018/9/20

Y1 - 2018/9/20

N2 - A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.

AB - A new strategy towards tubular hydrogen-bonded polymers based on the self-assembly of isocytosine tautomers in orthogonal directions is proposed and experimentally verified, including by 1H fast magic-angle spinning (MAS) solid-state NMR. The molecular tubes obtained possess large internal diameter and tailor-made outer functionalities rendering them potential candidates for a number of applications.

KW - fullerenes

KW - hydrogen-bond

KW - molecular tubes

KW - self-assembly

KW - solid-state NMR

U2 - 10.1002/chem.201803701

DO - 10.1002/chem.201803701

M3 - Article

C2 - 30070741

AN - SCOPUS:85053461363

SN - 0947-6539

VL - 24

SP - 14028

EP - 14033

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 53

ER -

A Tautoleptic Approach to Chiral Hydrogen-Bonded Supramolecular Tubular Polymers with Large Cavity

Abstract

Subject classification (UKÄ)

Free keywords

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