Absolute Cooling Rates of Freely Decaying Fullerenes

A. E. K. Sunden, M. Goto, J. Matsumoto, H. Shiromaru, H. Tanuma, T. Azuma, J. U. Andersen, Sophie Canton, K. Hansen

Research output: Contribution to journalArticlepeer-review

15 Citations (SciVal)

Abstract

The cooling rates of C-60(-) have been measured in an electrostatic storage ring between several hundred mu s and several tens of ms with one-photon laser excitation. The absolute energy scale is established by the photon energy, and the cooling time interval is derived from the nonexponential decay of the ensemble of hot molecules. The energy decreases due to the combined action of depletion and thermal emission of IR photons with a total energy loss rate that varies inversely proportional to time, 0.9 eV/t. The radiative component decreases from a few hundred eV/s at submillisecond time scales to several tens of eV/s at 20 ms and confirms that the crossover from depletion to predominantly radiative cooling occurs around 5 ms. The method is applicable to any large molecule or cluster which decays spontaneously, irrespective of the specific decay channel.
Original languageEnglish
JournalPhysical Review Letters
Volume103
Issue number14
DOIs
Publication statusPublished - 2009

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

  • Atom and Molecular Physics and Optics

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