Calibration factor for determination of interstitial oxygen concentration in germanium by infrared absorption

V V Litvinov, B G Svensson, L I Murin, Lennart Lindström, V P Markevich

Research output: Contribution to journalArticlepeer-review

Abstract

Intensities of infrared absorption due to asymmetric stretching vibrations of interstitial oxygen atoms in Ge crystals enriched with O-16 and O-18 isotopes have been compared with oxygen concentrations determined by means of secondary ion mass spectrometry (SIMS). For Ge samples with oxygen content less than 510(17) cm(-3) a good correlation has been found between the values of oxygen concentration and values of absorption coefficient in maximum of the absorption band at 855.6 cm(-1) with a proportionality coefficient C-O = 0.95 10(17) cm(-2). It is argued that kinetics of oxygen-related thermal double donor formation and oxygen loss upon heat-treatments of Ge crystals at 350 degrees C cannot be described properly with the application of calibration coefficient C-O 510(16) cm(-2), which is widely used for the determination of oxygen concentration in Ge crystals.
Original languageEnglish
Pages (from-to)735-740
JournalSolid State Phenomena
Volume108-109
Publication statusPublished - 2005

Subject classification (UKÄ)

  • Condensed Matter Physics

Free keywords

  • SIMS
  • oxygen
  • germanium
  • infrared absorption

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