Charge Carrier Dynamics of Polymer: Fullerene Blends: From Geminate to Non-Geminate Recombination

Dimali Vithanage, Ergang Wang, Zhongqiang Wang, Fei Ma, Olle Inganas, Mats R. Andersson, Arkady Yartsev, Villy Sundström, Torbjörn Pascher

Research output: Contribution to journalArticlepeer-review

15 Citations (SciVal)

Abstract

The charge carrier dynamics of a new polymer-fullerene blend are examined on the femtosecond to the millisecond time scale. The full time range is globally fitted using a chemical reaction rate model that includes all key processes, charge generation, energy transfer, charge separation, and recombination, over the full 12 orders of magnitude in time and a factor of 33 in light intensity. Particular attention is paid to the charge recombination processes and it is found that they are highly material specific. Comparison of the dynamics to those of a previously studied polymer: fullerene blend reveals that while for one blend the recombination dynamics are mainly controlled by geminate recombination, the charge recombination in the presently studied polymer: fullerene blend are entirely controlled by non-geminate electron-hole recombination. Carrier density dependence of the non-geminate recombination rate is analyzed and a correlated disorder model of site energies is proposed to explain the observed dependency.
Original languageEnglish
Article number1301706
JournalAdvanced Energy Materials
Volume4
Issue number8
DOIs
Publication statusPublished - 2014

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

  • Atom and Molecular Physics and Optics

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