cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

Christian Hansson, Åke Oskarsson

Research output: Contribution to journalArticlepeer-review

Abstract

The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).
Original languageEnglish
Pages (from-to)M61-M63
JournalActa Crystallographica. Section C: Crystal Structure Communications
Volume64
DOIs
Publication statusPublished - 2008

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

Subject classification (UKÄ)

  • Organic Chemistry

Keywords

  • platinum compounds
  • data mining
  • crystallography

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