cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

Christian Hansson; Åke Oskarsson

doi:10.1107/S0108270107061902

cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

Christian Hansson, Åke Oskarsson

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).

Original language	English
Pages (from-to)	M61-M63
Journal	Acta Crystallographica. Section C: Crystal Structure Communications
Volume	64
DOIs	https://doi.org/10.1107/S0108270107061902
Publication status	Published - 2008

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

Subject classification (UKÄ)

Organic Chemistry

Free keywords

platinum compounds
data mining
crystallography

Access to Document

10.1107/S0108270107061902

Cite this

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title = "cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)",

abstract = "The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) {\AA}]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).",

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note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)",

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doi = "10.1107/S0108270107061902",

language = "English",

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journal = "Acta Crystallographica. Section C: Crystal Structure Communications",

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T1 - cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

AU - Hansson, Christian

AU - Oskarsson, Åke

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

PY - 2008

Y1 - 2008

N2 - The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).

AB - The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).

KW - platinum compounds

KW - data mining

KW - crystallography

U2 - 10.1107/S0108270107061902

DO - 10.1107/S0108270107061902

M3 - Article

C2 - 18216443

SN - 0108-2701

VL - 64

SP - M61-M63

JO - Acta Crystallographica. Section C: Crystal Structure Communications

JF - Acta Crystallographica. Section C: Crystal Structure Communications

ER -

cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

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