Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

Lars Ivar Elding; Ebbe Nordlander; Keranio Kiriakidou; Maria R.  Plutino; Fabio Prestopino; Magda Monari; Maria Johansson; Esteve Valls; Roberto Gobetto; Silvio Aime

doi:10.1039/a807222a

Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

Lars Ivar Elding, Ebbe Nordlander, Keranio Kiriakidou, Maria R. Plutino, Fabio Prestopino, Magda Monari, Maria Johansson, Esteve Valls, Roberto Gobetto, Silvio Aime

Research output: Contribution to journal › Article › peer-review

Abstract

Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.

Original language	English
Pages (from-to)	2721 - 2722
Number of pages	2
Journal	Chemical Communications
Volume	1998
Issue number	24
DOIs	https://doi.org/10.1039/a807222a
Publication status	Published - 1998

Subject classification (UKÄ)

Inorganic Chemistry

Free keywords

Osmium carbonyls
Cluster complex
Addition Reactions
Kinetics
Reaction mechanism

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10.1039/a807222a

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@article{d52ac03159aa498ea769a1668a23c735,

title = "Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters",

abstract = "Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.",

keywords = "Osmium carbonyls, Cluster complex, Addition Reactions, Kinetics, Reaction mechanism",

author = "Elding, \{Lars Ivar\} and Ebbe Nordlander and Keranio Kiriakidou and Plutino, \{Maria R.\} and Fabio Prestopino and Magda Monari and Maria Johansson and Esteve Valls and Roberto Gobetto and Silvio Aime",

year = "1998",

doi = "10.1039/a807222a",

language = "English",

volume = "1998",

pages = "2721 -- 2722",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "24",

}

TY - JOUR

T1 - Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

AU - Elding, Lars Ivar

AU - Nordlander, Ebbe

AU - Kiriakidou, Keranio

AU - Plutino, Maria R.

AU - Prestopino, Fabio

AU - Monari, Magda

AU - Johansson, Maria

AU - Valls, Esteve

AU - Gobetto, Roberto

AU - Aime, Silvio

PY - 1998

Y1 - 1998

N2 - Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.

AB - Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.

KW - Osmium carbonyls

KW - Cluster complex

KW - Addition Reactions

KW - Kinetics

KW - Reaction mechanism

UR - https://www.scopus.com/pages/publications/0032556748

U2 - 10.1039/a807222a

DO - 10.1039/a807222a

M3 - Article

SN - 1364-548X

VL - 1998

SP - 2721

EP - 2722

JO - Chemical Communications

JF - Chemical Communications

IS - 24

ER -

Detection of a Novel Intermediate in the Addition of Thiols to Osmium Carbonyl Clusters

Abstract

Subject classification (UKÄ)

Free keywords

Access to Document

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