Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis.

Murtaza Hyder; Lidia Luque Aguilar; Johan Genberg; Margareta Sandahl; Clas Wesén; Jan Åke Jönsson

doi:10.1016/j.talanta.2011.04.080

Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis.

Murtaza Hyder, Lidia Luque Aguilar, Johan Genberg, Margareta Sandahl, Clas Wesén, Jan Åke Jönsson

Research output: Contribution to journal › Article › peer-review

Abstract

A method for determination of polycyclic aromatic hydrocarbons (PAHs) from aerosols was developed. Instead of conventionally used non-polar or slightly polar phenylmethylpolysiloxane column a highly polar, highly substituted, cyanopropyl column (VF-23 MS) was used for separation of PAHs. Based on hollow fiber micro-porous membrane liquid-liquid extraction (HF-MMLLE) a method was developed for sample clean up and pretreatment. An enrichment factor of 617-1022 was obtained with extraction efficiency 10.2-18.9% for different PAHs analyzed in this study. The optimized method was successfully applied to aerosol samples and limits of detection between 1.2pgm(-3) and 180pgm(-3) was obtained. Almost all PAHs were found in most of the aerosol samples.

Original language	English
Pages (from-to)	919-926
Journal	Talanta
Volume	85
Issue number	2
DOIs	https://doi.org/10.1016/j.talanta.2011.04.080
Publication status	Published - 2011

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Nuclear Physics (Faculty of Science) (011013004)

Subject classification (UKÄ)

Subatomic Physics
Organic Chemistry

Keywords

Extraction
Hollow fiber
Enrichment factor
Aerosol
Polycyclic
aromatic hydrocarbons

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10.1016/j.talanta.2011.04.080

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Hyder, M., Aguilar, L. L., Genberg, J., Sandahl, M., Wesén, C., & Jönsson, J. Å. (2011). Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis. Talanta, 85(2), 919-926. https://doi.org/10.1016/j.talanta.2011.04.080

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title = "Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis.",

abstract = "A method for determination of polycyclic aromatic hydrocarbons (PAHs) from aerosols was developed. Instead of conventionally used non-polar or slightly polar phenylmethylpolysiloxane column a highly polar, highly substituted, cyanopropyl column (VF-23 MS) was used for separation of PAHs. Based on hollow fiber micro-porous membrane liquid-liquid extraction (HF-MMLLE) a method was developed for sample clean up and pretreatment. An enrichment factor of 617-1022 was obtained with extraction efficiency 10.2-18.9% for different PAHs analyzed in this study. The optimized method was successfully applied to aerosol samples and limits of detection between 1.2pgm(-3) and 180pgm(-3) was obtained. Almost all PAHs were found in most of the aerosol samples.",

keywords = "Extraction, Hollow fiber, Enrichment factor, Aerosol, Polycyclic, aromatic hydrocarbons",

author = "Murtaza Hyder and Aguilar, {Lidia Luque} and Johan Genberg and Margareta Sandahl and Clas Wes{\'e}n and J{\"o}nsson, {Jan {\AA}ke}",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Nuclear Physics (Faculty of Science) (011013004)",

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Hyder, M, Aguilar, LL, Genberg, J, Sandahl, M, Wesén, C & Jönsson, JÅ 2011, 'Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis.', Talanta, vol. 85, no. 2, pp. 919-926. https://doi.org/10.1016/j.talanta.2011.04.080

Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis. / Hyder, Murtaza; Aguilar, Lidia Luque; Genberg, Johan et al.

In: Talanta, Vol. 85, No. 2, 2011, p. 919-926.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Determination of polycyclic aromatic hydrocarbons (PAHs) from organic aerosols using hollow fiber micro - porous membrane liquid - liquid extraction (HF-MMLLE) followed by gas chromatography-mass spectrometry analysis.

AU - Hyder, Murtaza

AU - Aguilar, Lidia Luque

AU - Genberg, Johan

AU - Sandahl, Margareta

AU - Wesén, Clas

AU - Jönsson, Jan Åke

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Nuclear Physics (Faculty of Science) (011013004)

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AB - A method for determination of polycyclic aromatic hydrocarbons (PAHs) from aerosols was developed. Instead of conventionally used non-polar or slightly polar phenylmethylpolysiloxane column a highly polar, highly substituted, cyanopropyl column (VF-23 MS) was used for separation of PAHs. Based on hollow fiber micro-porous membrane liquid-liquid extraction (HF-MMLLE) a method was developed for sample clean up and pretreatment. An enrichment factor of 617-1022 was obtained with extraction efficiency 10.2-18.9% for different PAHs analyzed in this study. The optimized method was successfully applied to aerosol samples and limits of detection between 1.2pgm(-3) and 180pgm(-3) was obtained. Almost all PAHs were found in most of the aerosol samples.

KW - Extraction

KW - Hollow fiber

KW - Enrichment factor

KW - Aerosol

KW - Polycyclic

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