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DFT Investigation of the Mechanism of Phosphine-Thioether Isomerization in the Triosmium Cluster Os-3(CO)(10)(Ph2PCH2CH2SMe): Migratory Preference for the Formation of an Edge-Bridged Thioether versus a Phosphine Moiety

David A. Hrovat, Ebbe Nordlander, Michael G. Richmond

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Biochemistry, Genetics and Molecular Biology