Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Ahmed Abdel-Magied, Amrendra Singh, Matti Haukka, Michael G Richmond, Ebbe Nordlander

Research output: Contribution to journalArticlepeer-review

7 Citations (SciVal)

Abstract

Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.
Original languageEnglish
Pages (from-to)7705-7708
JournalChemical Communications
Volume50
Issue number57
DOIs
Publication statusPublished - 2014

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

  • Chemical Sciences

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