Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Ahmed Abdel-Magied; Amrendra Singh; Matti Haukka; Michael G Richmond; Ebbe Nordlander

doi:10.1039/c4cc02319f

Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Ahmed Abdel-Magied, Amrendra Singh, Matti Haukka, Michael G Richmond, Ebbe Nordlander

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.

Original language	English
Pages (from-to)	7705-7708
Journal	Chemical Communications
Volume	50
Issue number	57
DOIs	https://doi.org/10.1039/c4cc02319f
Publication status	Published - 2014

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Chemical Sciences

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10.1039/c4cc02319f

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title = "Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.",

abstract = "Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.",

author = "Ahmed Abdel-Magied and Amrendra Singh and Matti Haukka and Richmond, \{Michael G\} and Ebbe Nordlander",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

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AU - Singh, Amrendra

AU - Haukka, Matti

AU - Richmond, Michael G

AU - Nordlander, Ebbe

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2014

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N2 - Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.

AB - Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P-P*)] (P-P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations.

UR - https://www.scopus.com/pages/publications/84903183517

U2 - 10.1039/c4cc02319f

DO - 10.1039/c4cc02319f

M3 - Article

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SN - 1364-548X

VL - 50

SP - 7705

EP - 7708

JO - Chemical Communications

JF - Chemical Communications

IS - 57

ER -

Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis.

Abstract

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