Electron microscopy study of single crystal BaZr0.9Y0.1O3-x films prepared by chemical solution deposition

Filip Lenrick; D. Griesche; J. -W. Kim; T. Schneller; Reine Wallenberg

doi:10.1149/1.3701300

Electron microscopy study of single crystal BaZr0.9Y0.1O3-x films prepared by chemical solution deposition

Filip Lenrick, D. Griesche, J. -W. Kim, T. Schneller, Reine Wallenberg

Centre for Analysis and Synthesis

Research output: Chapter in Book/Report/Conference proceeding › Paper in conference proceeding › peer-review

Abstract

Single crystal thin films of 10% yttrium doped barium zirconate (BZY10) have been prepared using chemical solution deposition on magnesium oxide substrates and annealed at 800 or 1000 degrees C. A focused ion beam lift out technique was used to prepare thin (< 100 nm) specimens for transmission electron microscopy (TEM) analysis. A variety of TEM based techniques were used for characterization, including high resolution imaging, X-ray energy dispersive spectroscopy and energy filtered TEM. High resolution TEM imaging indicated a high quality single crystal film with an epitaxial cube on cube type interface between BZY10 and MgO. For the sample annealed 1000 degrees C, annular dark field imaging in scanning transmission electron microscopy (STEM) mode showed a layered pattern of lower intensity in the single crystal film. Energy filtered TEM thickness map together with scanning electron microscopy (SEM) indicate the pattern consists of partially repeating voids.

Original language	English
Title of host publication	ECS Transactions
Publisher	Electrochemical Society
Pages	121-127
Volume	45
DOIs	https://doi.org/10.1149/1.3701300
Publication status	Published - 2012
Event	Symposium on Ionic and Mixed Conducting Ceramics 8 - Seattle, WA Duration: 2012 May 6 → 2012 May 10

Publication series

Name
Number	1
Volume	45
ISSN (Print)	1938-6737
ISSN (Electronic)	1938-5862

Conference

Conference	Symposium on Ionic and Mixed Conducting Ceramics 8
Period	2012/05/06 → 2012/05/10

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)

Subject classification (UKÄ)

Chemical Sciences

Access to Document

10.1149/1.3701300

Cite this

@inproceedings{ceef3f9948c642c5b04be124d77aa7c6,

title = "Electron microscopy study of single crystal BaZr0.9Y0.1O3-x films prepared by chemical solution deposition",

abstract = "Single crystal thin films of 10\% yttrium doped barium zirconate (BZY10) have been prepared using chemical solution deposition on magnesium oxide substrates and annealed at 800 or 1000 degrees C. A focused ion beam lift out technique was used to prepare thin (< 100 nm) specimens for transmission electron microscopy (TEM) analysis. A variety of TEM based techniques were used for characterization, including high resolution imaging, X-ray energy dispersive spectroscopy and energy filtered TEM. High resolution TEM imaging indicated a high quality single crystal film with an epitaxial cube on cube type interface between BZY10 and MgO. For the sample annealed 1000 degrees C, annular dark field imaging in scanning transmission electron microscopy (STEM) mode showed a layered pattern of lower intensity in the single crystal film. Energy filtered TEM thickness map together with scanning electron microscopy (SEM) indicate the pattern consists of partially repeating voids.",

author = "Filip Lenrick and D. Griesche and Kim, \{J. -W.\} and T. Schneller and Reine Wallenberg",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041); Symposium on Ionic and Mixed Conducting Ceramics 8 ; Conference date: 06-05-2012 Through 10-05-2012",

year = "2012",

doi = "10.1149/1.3701300",

language = "English",

volume = "45",

publisher = "Electrochemical Society",

number = "1",

pages = "121--127",

booktitle = "ECS Transactions",

address = "United States",

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TY - GEN

T1 - Electron microscopy study of single crystal BaZr0.9Y0.1O3-x films prepared by chemical solution deposition

AU - Lenrick, Filip

AU - Griesche, D.

AU - Kim, J. -W.

AU - Schneller, T.

AU - Wallenberg, Reine

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)

PY - 2012

Y1 - 2012

N2 - Single crystal thin films of 10% yttrium doped barium zirconate (BZY10) have been prepared using chemical solution deposition on magnesium oxide substrates and annealed at 800 or 1000 degrees C. A focused ion beam lift out technique was used to prepare thin (< 100 nm) specimens for transmission electron microscopy (TEM) analysis. A variety of TEM based techniques were used for characterization, including high resolution imaging, X-ray energy dispersive spectroscopy and energy filtered TEM. High resolution TEM imaging indicated a high quality single crystal film with an epitaxial cube on cube type interface between BZY10 and MgO. For the sample annealed 1000 degrees C, annular dark field imaging in scanning transmission electron microscopy (STEM) mode showed a layered pattern of lower intensity in the single crystal film. Energy filtered TEM thickness map together with scanning electron microscopy (SEM) indicate the pattern consists of partially repeating voids.

AB - Single crystal thin films of 10% yttrium doped barium zirconate (BZY10) have been prepared using chemical solution deposition on magnesium oxide substrates and annealed at 800 or 1000 degrees C. A focused ion beam lift out technique was used to prepare thin (< 100 nm) specimens for transmission electron microscopy (TEM) analysis. A variety of TEM based techniques were used for characterization, including high resolution imaging, X-ray energy dispersive spectroscopy and energy filtered TEM. High resolution TEM imaging indicated a high quality single crystal film with an epitaxial cube on cube type interface between BZY10 and MgO. For the sample annealed 1000 degrees C, annular dark field imaging in scanning transmission electron microscopy (STEM) mode showed a layered pattern of lower intensity in the single crystal film. Energy filtered TEM thickness map together with scanning electron microscopy (SEM) indicate the pattern consists of partially repeating voids.

UR - https://www.scopus.com/pages/publications/84869007905

U2 - 10.1149/1.3701300

DO - 10.1149/1.3701300

M3 - Paper in conference proceeding

VL - 45

SP - 121

EP - 127

BT - ECS Transactions

PB - Electrochemical Society

T2 - Symposium on Ionic and Mixed Conducting Ceramics 8

Y2 - 6 May 2012 through 10 May 2012

ER -

Electron microscopy study of single crystal BaZr0.9Y0.1O3-x films prepared by chemical solution deposition

Abstract

Publication series

Conference

Bibliographical note

Subject classification (UKÄ)

Access to Document

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