Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts

R. K. Grasselli; C. G. Lugmair; A. F. Volpe Jr.; Arne Andersson; J.D. Burrington

doi:10.1016/j.cattod.2010.01.044

Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts

R. K. Grasselli, C. G. Lugmair, A. F. Volpe Jr., Arne Andersson, J.D. Burrington

Division of Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.

Original language	English
Pages (from-to)	33-38
Journal	Catalysis Today
Volume	157
Issue number	1-4
DOIs	https://doi.org/10.1016/j.cattod.2010.01.044
Publication status	Published - 2010

Subject classification (UKÄ)

Chemical Engineering

Free keywords

propylene
M1/M2
propane
acrylic acid

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10.1016/j.cattod.2010.01.044

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title = "Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts",

abstract = "Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15\%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.",

keywords = "propylene, M1/M2, propane, acrylic acid",

author = "Grasselli, \{R. K.\} and Lugmair, \{C. G.\} and \{Volpe Jr.\}, \{A. F.\} and Arne Andersson and J.D. Burrington",

year = "2010",

doi = "10.1016/j.cattod.2010.01.044",

language = "English",

volume = "157",

pages = "33--38",

journal = "Catalysis Today",

issn = "0920-5861",

publisher = "Elsevier",

number = "1-4",

}

TY - JOUR

T1 - Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts

AU - Grasselli, R. K.

AU - Lugmair, C. G.

AU - Volpe Jr., A. F.

AU - Andersson, Arne

AU - Burrington, J.D.

PY - 2010

Y1 - 2010

N2 - Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.

AB - Selective doping of (M1) Mo7.8V1.2NbTe0.94O28.9 and (M2) Mo4.67V1.33Te1.82O19.82 phases with P significantly enhance acrylic acid yields (2-15%) in propane/propylene oxidation. Amorphous overlayers (Te-molybdate) seriously inhibit acrylic acid formation. Detailed mechanisms are presented.

KW - propylene

KW - M1/M2

KW - propane

KW - acrylic acid

UR - https://www.scopus.com/pages/publications/78049245357

U2 - 10.1016/j.cattod.2010.01.044

DO - 10.1016/j.cattod.2010.01.044

M3 - Article

SN - 0920-5861

VL - 157

SP - 33

EP - 38

JO - Catalysis Today

JF - Catalysis Today

IS - 1-4

ER -

Enhancement of acrylic acid yields in propane and propylene oxidation by selective P doping of MoV(Nb)TeO-based M1 and M2 catalysts

Abstract

Subject classification (UKÄ)

Free keywords

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