Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.

Mainak Mitra; Julio Lloret-Fillol; Matti Haukka; Miquel Costas; Ebbe Nordlander

doi:10.1039/c3cc47830k

Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.

Mainak Mitra, Julio Lloret-Fillol, Matti Haukka, Miquel Costas, Ebbe Nordlander

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.

Original language	English
Pages (from-to)	1408-1410
Journal	Chemical Communications
Volume	50
Issue number	12
DOIs	https://doi.org/10.1039/c3cc47830k
Publication status	Published - 2014

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

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Chemical Sciences

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10.1039/c3cc47830k

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title = "Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.",

abstract = "A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.",

author = "Mainak Mitra and Julio Lloret-Fillol and Matti Haukka and Miquel Costas and Ebbe Nordlander",

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AU - Mitra, Mainak

AU - Lloret-Fillol, Julio

AU - Haukka, Matti

AU - Costas, Miquel

AU - Nordlander, Ebbe

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2014

Y1 - 2014

N2 - A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.

AB - A new iron complex mediates stereospecific hydroxylation of alkyl C-H bonds with hydrogen peroxide, exhibiting excellent efficiency. Isotope labelling studies provide evidence that the relative reactivity of tautomerically related oxo-iron species responsible for the C-H hydroxylation reaction is dominated by steric factors.

UR - https://www.scopus.com/pages/publications/84892609738

U2 - 10.1039/c3cc47830k

DO - 10.1039/c3cc47830k

M3 - Article

SN - 1364-548X

VL - 50

SP - 1408

EP - 1410

JO - Chemical Communications

JF - Chemical Communications

IS - 12

ER -

Evidence that steric factors modulate reactivity of tautomeric iron-oxo species in stereospecific alkane C-H hydroxylation.

Abstract

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