Hetero Face-to-Face Porphyrin Array with Cooperative Effects of Coordination and Host–Guest Complexation

Yusuke Chiba; Maning Liu; Yasuhiro Tachibana; Tetsuaki Fujihara; Yasushi Tsuji; Jun Terao

doi:10.1002/asia.201700738

Hetero Face-to-Face Porphyrin Array with Cooperative Effects of Coordination and Host–Guest Complexation

Yusuke Chiba, Maning Liu, Yasuhiro Tachibana, Tetsuaki Fujihara, Yasushi Tsuji, Jun Terao

Research output: Contribution to journal › Article › peer-review

Abstract

We successfully synthesized a hetero face-to-face porphyrin array composed of ZnTPP and RuTPP(DABCO)₂ (TPP: 5, 10, 15, 20-tetraphenylporphyrin, DABCO: 1,4-diazabi-cyclo[2.2.2]octane) in 2:1 molar ratio. A cyclic Zn porphyrin dimer (ZnCP) was also used as the host molecule for the Ru porphyrin. In the latter, the Ru-DABCO bonding in RuTPP(DABCO)₂ was stabilized by the host-guest complexation. Reaction progress kinetic analysis of the ligand substitution reaction of RuTPP(DABCO)₂ and that in ZnCP revealed the stabilization mechanism of the Ru-DABCO bonding. Photoinduced electron transfer (PET) from the Zn porphyrin to the Ru porphyrin was observed in the porphyrin array. The host-guest stabilization of unstable complex for construction of a donor—acceptor–donor structure is expected to be a new method for an artificial photosynthesis.

Original language	English
Pages (from-to)	1900-1904
Number of pages	5
Journal	Chemistry - An Asian Journal
Volume	12
Issue number	15
DOIs	https://doi.org/10.1002/asia.201700738
Publication status	Published - 2017 Aug 4
Externally published	Yes

Subject classification (UKÄ)

Materials Chemistry

Free keywords

artificial photosynthesis
coordination bonding
donor-acceptor systems
host-guest systems
photoinduced electron transfer
porphyrin

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10.1002/asia.201700738

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@article{02735f0d1689409e92ad02ad68891cde,

title = "Hetero Face-to-Face Porphyrin Array with Cooperative Effects of Coordination and Host–Guest Complexation",

abstract = "We successfully synthesized a hetero face-to-face porphyrin array composed of ZnTPP and RuTPP(DABCO)2 (TPP: 5, 10, 15, 20-tetraphenylporphyrin, DABCO: 1,4-diazabi-cyclo[2.2.2]octane) in 2:1 molar ratio. A cyclic Zn porphyrin dimer (ZnCP) was also used as the host molecule for the Ru porphyrin. In the latter, the Ru-DABCO bonding in RuTPP(DABCO)2 was stabilized by the host-guest complexation. Reaction progress kinetic analysis of the ligand substitution reaction of RuTPP(DABCO)2 and that in ZnCP revealed the stabilization mechanism of the Ru-DABCO bonding. Photoinduced electron transfer (PET) from the Zn porphyrin to the Ru porphyrin was observed in the porphyrin array. The host-guest stabilization of unstable complex for construction of a donor—acceptor–donor structure is expected to be a new method for an artificial photosynthesis.",

keywords = "artificial photosynthesis, coordination bonding, donor-acceptor systems, host-guest systems, photoinduced electron transfer, porphyrin",

author = "Yusuke Chiba and Maning Liu and Yasuhiro Tachibana and Tetsuaki Fujihara and Yasushi Tsuji and Jun Terao",

year = "2017",

month = aug,

day = "4",

doi = "10.1002/asia.201700738",

language = "English",

volume = "12",

pages = "1900--1904",

journal = "Chemistry - An Asian Journal",

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publisher = "John Wiley & Sons Inc.",

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T1 - Hetero Face-to-Face Porphyrin Array with Cooperative Effects of Coordination and Host–Guest Complexation

AU - Chiba, Yusuke

AU - Liu, Maning

AU - Tachibana, Yasuhiro

AU - Fujihara, Tetsuaki

AU - Tsuji, Yasushi

AU - Terao, Jun

PY - 2017/8/4

Y1 - 2017/8/4

N2 - We successfully synthesized a hetero face-to-face porphyrin array composed of ZnTPP and RuTPP(DABCO)2 (TPP: 5, 10, 15, 20-tetraphenylporphyrin, DABCO: 1,4-diazabi-cyclo[2.2.2]octane) in 2:1 molar ratio. A cyclic Zn porphyrin dimer (ZnCP) was also used as the host molecule for the Ru porphyrin. In the latter, the Ru-DABCO bonding in RuTPP(DABCO)2 was stabilized by the host-guest complexation. Reaction progress kinetic analysis of the ligand substitution reaction of RuTPP(DABCO)2 and that in ZnCP revealed the stabilization mechanism of the Ru-DABCO bonding. Photoinduced electron transfer (PET) from the Zn porphyrin to the Ru porphyrin was observed in the porphyrin array. The host-guest stabilization of unstable complex for construction of a donor—acceptor–donor structure is expected to be a new method for an artificial photosynthesis.

AB - We successfully synthesized a hetero face-to-face porphyrin array composed of ZnTPP and RuTPP(DABCO)2 (TPP: 5, 10, 15, 20-tetraphenylporphyrin, DABCO: 1,4-diazabi-cyclo[2.2.2]octane) in 2:1 molar ratio. A cyclic Zn porphyrin dimer (ZnCP) was also used as the host molecule for the Ru porphyrin. In the latter, the Ru-DABCO bonding in RuTPP(DABCO)2 was stabilized by the host-guest complexation. Reaction progress kinetic analysis of the ligand substitution reaction of RuTPP(DABCO)2 and that in ZnCP revealed the stabilization mechanism of the Ru-DABCO bonding. Photoinduced electron transfer (PET) from the Zn porphyrin to the Ru porphyrin was observed in the porphyrin array. The host-guest stabilization of unstable complex for construction of a donor—acceptor–donor structure is expected to be a new method for an artificial photosynthesis.

KW - artificial photosynthesis

KW - coordination bonding

KW - donor-acceptor systems

KW - host-guest systems

KW - photoinduced electron transfer

KW - porphyrin

U2 - 10.1002/asia.201700738

DO - 10.1002/asia.201700738

M3 - Article

C2 - 28544526

AN - SCOPUS:85021769698

SN - 1861-4728

VL - 12

SP - 1900

EP - 1904

JO - Chemistry - An Asian Journal

JF - Chemistry - An Asian Journal

IS - 15

ER -

Hetero Face-to-Face Porphyrin Array with Cooperative Effects of Coordination and Host–Guest Complexation

Abstract

Subject classification (UKÄ)

Free keywords

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