Hexakis(tetraaquasodium) decavanadate(V) dihydrate

Jessica Nilsson; Ebbe Nordlander; Ulrich Behrens; Dieter Rehder

doi:10.1107/S1600536810010251

Hexakis(tetraaquasodium) decavanadate(V) dihydrate

Jessica Nilsson, Ebbe Nordlander, Ulrich Behrens, Dieter Rehder

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.

Original language	English
Pages (from-to)	I30-U148
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
DOIs	https://doi.org/10.1107/S1600536810010251
Publication status	Published - 2010

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Access to Document

10.1107/S1600536810010251

Cite this

@article{64a56dff4d554a55921fff7f2516fc68,

title = "Hexakis(tetraaquasodium) decavanadate(V) dihydrate",

abstract = "The title compound, \{[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O\}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [\{Na(H2O)(3)\}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[\{Na(H2O)(3)\}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.",

author = "Jessica Nilsson and Ebbe Nordlander and Ulrich Behrens and Dieter Rehder",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2010",

doi = "10.1107/S1600536810010251",

language = "English",

volume = "66",

pages = "I30--U148",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Hexakis(tetraaquasodium) decavanadate(V) dihydrate

AU - Nilsson, Jessica

AU - Nordlander, Ebbe

AU - Behrens, Ulrich

AU - Rehder, Dieter

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2010

Y1 - 2010

N2 - The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.

AB - The title compound, {[Na(H2O)(4)](6)[V10O28]center dot 2H(2)O}n, crystallized from a H2O/THF/CH3CN solution (pH ca 6)containing equimolar amounts of NaVO3 and N-(2-hydroxybenzyl)-N-(2-picolyl) glycine. In the crystal structure, the decavanadate [V10O28](6-) anion ((1) over bar symmetry)is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units. Interconnection of these aquasodium-ion-sandwiched decavanadates to chains parallel to [001]is effected by mu-[{Na(H2O)(3)}(2)(mu-H2O)(2)](2+) units, bridging adjacent decavanadates via O=V. The structure is consolidated by an extensive network of O-H center dot center dot center dot O hydrogen bonds.

UR - https://www.scopus.com/pages/publications/77951236065

U2 - 10.1107/S1600536810010251

DO - 10.1107/S1600536810010251

M3 - Article

C2 - 21580463

SN - 1600-5368

VL - 66

SP - I30-U148

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Hexakis(tetraaquasodium) decavanadate(V) dihydrate

Abstract

Bibliographical note

Subject classification (UKÄ)

Access to Document

Other files and links

Fingerprint

Cite this