Host-guest compounds in the family of tellurium-nickel oxohalogenides

Mats Johnsson, Sven Lidin, Karl W. Törnroos, Hans Beat Bürgi, Patrice Millet

Research output: Contribution to journalArticlepeer-review

25 Citations (SciVal)

Abstract

The peeling of an onion: Embedded in the voids of an infinite cationic [Te32Ni30X3O90]5+ network lies an icosahedral [Ni4X13]5- anionic guest cluster (ochre). It may be considered wrapped and trapped in a successive series of concentric skins made from the lone pairs of Te atoms (blue), the Te (yellow), O (red), and Ni atoms (light blue polyhedra). But are there any other guests?

Original languageEnglish
Pages (from-to)4292-4295
Number of pages4
JournalAngewandte Chemie - International Edition
Volume43
Issue number33
DOIs
Publication statusPublished - 2004 Aug 20
Externally publishedYes

Keywords

  • Cluster compounds
  • Host-guest systems
  • Supramolecular chemistry
  • Tellurium

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