Incommensurately Modulated δ″-Au1+xCd2-x Formed by an Unquenchable Phase Transformation from the γ-Brass δ'-Phase.

Partha Jana; Sven Lidin

doi:10.1021/ic4013608

Incommensurately Modulated δ″-Au1+xCd2-x Formed by an Unquenchable Phase Transformation from the γ-Brass δ'-Phase.

Partha Jana, Sven Lidin

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and structural determination of the compound δ″-Au1+xCd2-x (0.07 ≤ x ≤0.08) is reported. The structure may be formally derived from that of ξ-CoZn13, but elemental ordering causes an incommensurate modulation as determined by single-crystal X-ray diffraction at room temperature. The compound δ″-Au3.23Cd5.76 crystallizes in the monoclinic super space group C2/m(0β(1)/2)00 with lattice parameters a = 14.790(2) Å, b = 8.251(1) Å, c = 12.744(1) Å, β = 115.182(9)° and a q-vector q = (0β(1)/2), β = 0.579b*. The δ″-phase is stable up to 652(1) K.

Original language	English
Pages (from-to)	12980-12985
Journal	Inorganic Chemistry
Volume	52
Issue number	22
DOIs	https://doi.org/10.1021/ic4013608
Publication status	Published - 2013

Subject classification (UKÄ)

Chemical Sciences

Access to Document

10.1021/ic4013608

Cite this

@article{d2ef76579e6748e9bf7c327d505dce35,

title = "Incommensurately Modulated δ″-Au1+xCd2-x Formed by an Unquenchable Phase Transformation from the γ-Brass δ'-Phase.",

abstract = "The synthesis and structural determination of the compound δ″-Au1+xCd2-x (0.07 ≤ x ≤0.08) is reported. The structure may be formally derived from that of ξ-CoZn13, but elemental ordering causes an incommensurate modulation as determined by single-crystal X-ray diffraction at room temperature. The compound δ″-Au3.23Cd5.76 crystallizes in the monoclinic super space group C2/m(0β(1)/2)00 with lattice parameters a = 14.790(2) {\AA}, b = 8.251(1) {\AA}, c = 12.744(1) {\AA}, β = 115.182(9)° and a q-vector q = (0β(1)/2), β = 0.579b*. The δ″-phase is stable up to 652(1) K.",

author = "Partha Jana and Sven Lidin",

year = "2013",

doi = "10.1021/ic4013608",

language = "English",

volume = "52",

pages = "12980--12985",

journal = "Inorganic Chemistry",

issn = "1520-510X",

publisher = "The American Chemical Society (ACS)",

number = "22",

}

TY - JOUR

T1 - Incommensurately Modulated δ″-Au1+xCd2-x Formed by an Unquenchable Phase Transformation from the γ-Brass δ'-Phase.

AU - Jana, Partha

AU - Lidin, Sven

PY - 2013

Y1 - 2013

N2 - The synthesis and structural determination of the compound δ″-Au1+xCd2-x (0.07 ≤ x ≤0.08) is reported. The structure may be formally derived from that of ξ-CoZn13, but elemental ordering causes an incommensurate modulation as determined by single-crystal X-ray diffraction at room temperature. The compound δ″-Au3.23Cd5.76 crystallizes in the monoclinic super space group C2/m(0β(1)/2)00 with lattice parameters a = 14.790(2) Å, b = 8.251(1) Å, c = 12.744(1) Å, β = 115.182(9)° and a q-vector q = (0β(1)/2), β = 0.579b*. The δ″-phase is stable up to 652(1) K.

AB - The synthesis and structural determination of the compound δ″-Au1+xCd2-x (0.07 ≤ x ≤0.08) is reported. The structure may be formally derived from that of ξ-CoZn13, but elemental ordering causes an incommensurate modulation as determined by single-crystal X-ray diffraction at room temperature. The compound δ″-Au3.23Cd5.76 crystallizes in the monoclinic super space group C2/m(0β(1)/2)00 with lattice parameters a = 14.790(2) Å, b = 8.251(1) Å, c = 12.744(1) Å, β = 115.182(9)° and a q-vector q = (0β(1)/2), β = 0.579b*. The δ″-phase is stable up to 652(1) K.

U2 - 10.1021/ic4013608

DO - 10.1021/ic4013608

M3 - Article

C2 - 24164380

SN - 1520-510X

VL - 52

SP - 12980

EP - 12985

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 22

ER -

Incommensurately Modulated δ″-Au1+xCd2-x Formed by an Unquenchable Phase Transformation from the γ-Brass δ'-Phase.

Abstract

Subject classification (UKÄ)

Access to Document

Fingerprint

Cite this