Insertion of carbon dioxide into (PCP)Pd-II-Me bonds

Roger Johansson; Martin Jarenmark; Ola Wendt

doi:10.1021/om0505561

Insertion of carbon dioxide into (PCP)Pd-II-Me bonds

Roger Johansson, Martin Jarenmark, Ola Wendt

Research output: Contribution to journal › Article › peer-review

Abstract

A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.

Original language	English
Pages (from-to)	4500-4502
Journal	Organometallics
Volume	24
Issue number	19
DOIs	https://doi.org/10.1021/om0505561
Publication status	Published - 2005

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Department of Chemistry (011001220)

Subject classification (UKÄ)

Organic Chemistry

Access to Document

10.1021/om0505561

Cite this

@article{4fc81e3dcc0d4bc0bab9177cf52ef46f,

title = "Insertion of carbon dioxide into (PCP)Pd-II-Me bonds",

abstract = "A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.",

author = "Roger Johansson and Martin Jarenmark and Ola Wendt",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Department of Chemistry (011001220)",

year = "2005",

doi = "10.1021/om0505561",

language = "English",

volume = "24",

pages = "4500--4502",

journal = "Organometallics",

issn = "1520-6041",

publisher = "The American Chemical Society (ACS)",

number = "19",

}

TY - JOUR

T1 - Insertion of carbon dioxide into (PCP)Pd-II-Me bonds

AU - Johansson, Roger

AU - Jarenmark, Martin

AU - Wendt, Ola

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240), Department of Chemistry (011001220)

PY - 2005

Y1 - 2005

N2 - A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.

AB - A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.

U2 - 10.1021/om0505561

DO - 10.1021/om0505561

M3 - Article

SN - 1520-6041

VL - 24

SP - 4500

EP - 4502

JO - Organometallics

JF - Organometallics

IS - 19

ER -

Insertion of carbon dioxide into (PCP)Pd-II-Me bonds

Abstract

Bibliographical note

Subject classification (UKÄ)

Access to Document

Fingerprint

Cite this