Intramolecular vibronic dynamics in molecular solids: C60

Lisbeth Kjeldgaard; Tanel Käämbre; Joachim Schiessling; Ingrid Marenne; James N. O'Shea; Joachim Schnadt; Chris J. Glover; Mitsuru Nagasono; Dennis Nordlund; M. Gunnar Garnier; Limin Qian; Jan-Erik Rubensson; Petra Rudolf; Nils Mårtensson; Joseph Nordgren; Paul A. Brühwiler

doi:10.1103/PhysRevB.72.205414

Intramolecular vibronic dynamics in molecular solids: C60

Lisbeth Kjeldgaard, Tanel Käämbre, Joachim Schiessling, Ingrid Marenne, James N. O'Shea, Joachim Schnadt, Chris J. Glover, Mitsuru Nagasono, Dennis Nordlund, M. Gunnar Garnier, Limin Qian, Jan-Erik Rubensson, Petra Rudolf, Nils Mårtensson, Joseph Nordgren, Paul A. Brühwiler

Research output: Contribution to journal › Article › peer-review

Abstract

Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.

Original language	English
Article number	205414
Journal	Physical Review B (Condensed Matter and Materials Physics)
Volume	72
Issue number	20
DOIs	https://doi.org/10.1103/PhysRevB.72.205414
Publication status	Published - 2005

Subject classification (UKÄ)

Physical Sciences
Atom and Molecular Physics and Optics
Natural Sciences

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Kjeldgaard, L., Käämbre, T., Schiessling, J., Marenne, I., O'Shea, J. N., Schnadt, J., Glover, C. J., Nagasono, M., Nordlund, D., Garnier, M. G., Qian, L., Rubensson, J.-E., Rudolf, P., Mårtensson, N., Nordgren, J., & Brühwiler, P. A. (2005). Intramolecular vibronic dynamics in molecular solids: C60. Physical Review B (Condensed Matter and Materials Physics), 72(20), Article 205414. https://doi.org/10.1103/PhysRevB.72.205414

@article{df637402772644e8addb175c45a43c7b,

title = "Intramolecular vibronic dynamics in molecular solids: C60",

abstract = "Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.",

author = "Lisbeth Kjeldgaard and Tanel K{\"a}{\"a}mbre and Joachim Schiessling and Ingrid Marenne and O'Shea, {James N.} and Joachim Schnadt and Glover, {Chris J.} and Mitsuru Nagasono and Dennis Nordlund and Garnier, {M. Gunnar} and Limin Qian and Jan-Erik Rubensson and Petra Rudolf and Nils M{\aa}rtensson and Joseph Nordgren and Br{\"u}hwiler, {Paul A.}",

year = "2005",

doi = "10.1103/PhysRevB.72.205414",

language = "English",

volume = "72",

journal = "Physical Review B (Condensed Matter and Materials Physics)",

issn = "1098-0121",

publisher = "American Physical Society",

number = "20",

}

Kjeldgaard, L, Käämbre, T, Schiessling, J, Marenne, I, O'Shea, JN, Schnadt, J, Glover, CJ, Nagasono, M, Nordlund, D, Garnier, MG, Qian, L, Rubensson, J-E, Rudolf, P, Mårtensson, N, Nordgren, J & Brühwiler, PA 2005, 'Intramolecular vibronic dynamics in molecular solids: C60', Physical Review B (Condensed Matter and Materials Physics), vol. 72, no. 20, 205414. https://doi.org/10.1103/PhysRevB.72.205414

TY - JOUR

T1 - Intramolecular vibronic dynamics in molecular solids: C60

AU - Kjeldgaard, Lisbeth

AU - Käämbre, Tanel

AU - Schiessling, Joachim

AU - Marenne, Ingrid

AU - O'Shea, James N.

AU - Schnadt, Joachim

AU - Glover, Chris J.

AU - Nagasono, Mitsuru

AU - Nordlund, Dennis

AU - Garnier, M. Gunnar

AU - Qian, Limin

AU - Rubensson, Jan-Erik

AU - Rudolf, Petra

AU - Mårtensson, Nils

AU - Nordgren, Joseph

AU - Brühwiler, Paul A.

PY - 2005

Y1 - 2005

N2 - Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.

AB - Vibronic coupling in solid C60 has been investigated with a combination of resonant photoemission spectroscopy (RPES) and resonant inelastic x-ray scattering (RIXS). Excitation as a function of energy within the lowest unoccupied molecular orbital resonance yielded strong oscillations in intensity and dispersion in RPES, and a strong inelastic component in RIXS. Reconciling these two observations establishes that vibronic coupling in this core hole excitation leads to predominantly inelastic scattering and localization of the excited vibrations on the molecule on a femtosecond time scale. The coupling extends throughout the widths of the frontier valence bands.

U2 - 10.1103/PhysRevB.72.205414

DO - 10.1103/PhysRevB.72.205414

M3 - Article

SN - 1098-0121

VL - 72

JO - Physical Review B (Condensed Matter and Materials Physics)

JF - Physical Review B (Condensed Matter and Materials Physics)

IS - 20

M1 - 205414

ER -

Intramolecular vibronic dynamics in molecular solids: C60

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