Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.

Teddy Ercegovic; Andréas Meijer; Göran Magnusson; Ulf Ellervik

doi:10.1021/ol015547c

Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.

Teddy Ercegovic, Andréas Meijer, Göran Magnusson, Ulf Ellervik

Research output: Contribution to journal › Article › peer-review

Abstract

The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46−82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.

Original language	English
Pages (from-to)	913-915
Journal	Organic Letters
Volume	3
Issue number	6
DOIs	https://doi.org/10.1021/ol015547c
Publication status	Published - 2001

Subject classification (UKÄ)

Organic Chemistry

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10.1021/ol015547c

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title = "Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.",

abstract = "The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46−82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.",

author = "Teddy Ercegovic and Andr{\'e}as Meijer and G{\"o}ran Magnusson and Ulf Ellervik",

year = "2001",

doi = "10.1021/ol015547c",

language = "English",

volume = "3",

pages = "913--915",

journal = "Organic Letters",

issn = "1523-7052",

publisher = "The American Chemical Society (ACS)",

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T1 - Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.

AU - Ercegovic, Teddy

AU - Meijer, Andréas

AU - Magnusson, Göran

AU - Ellervik, Ulf

PY - 2001

Y1 - 2001

N2 - The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46−82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.

AB - The novel promoter system iodine monochloride/silver trifluoromethanesulfonate (ICl/AgOTf) was evaluated with various thioglycoside donors and saccharide acceptors, and O-glycosides were obtained in 46−82% yield. Several practical advantages of the ICl/AgOTf system over known promoter systems were observed, such as convenient handling of the reagents and absence of byproducts related to N-succinimide.

U2 - 10.1021/ol015547c

DO - 10.1021/ol015547c

M3 - Article

SN - 1523-7052

VL - 3

SP - 913

EP - 915

JO - Organic Letters

JF - Organic Letters

IS - 6

ER -

Iodine Monochloride/Silver Trifluoromethanesulfonate (ICl/AgOTf) as a convenient Promoter System for O-Glycoside Synthesis.

Abstract

Subject classification (UKÄ)

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