Iodo-oxyapatite, the first example from a new class of modulated apatites

Peter Alberius Henning; Sven Lidin; Vačlav Petříček

Iodo-oxyapatite, the first example from a new class of modulated apatites

Peter Alberius Henning, Sven Lidin, Vačlav Petříček

Research output: Contribution to journal › Article › peer-review

Abstract

Iodo-oxyapatite [pentadecacalcium iodide oxide nonaphosphate, Ca₁₅(PO₄)₉IO] was synthesized by a flux method and the structure was solved from single-crystal X-ray data. The crystal structure was refined in the space group P6₃/m [a = 9.567 (1), c = 20.754 (2) Å and Z = 2] to wR on F of 0.0459. Iodo-oxyapatite has a typical hexagonal apatite structure but the unit cell is tripled along the hexad owing to ordering of the iodide and oxide ions along this direction.

Original language	English
Pages (from-to)	165-169
Number of pages	5
Journal	Acta Crystallographica. Section B: Structural Science
Volume	55
Issue number	2
Publication status	Published - 1999 Apr 1
Externally published	Yes

Cite this

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title = "Iodo-oxyapatite, the first example from a new class of modulated apatites",

abstract = "Iodo-oxyapatite [pentadecacalcium iodide oxide nonaphosphate, Ca15(PO4)9IO] was synthesized by a flux method and the structure was solved from single-crystal X-ray data. The crystal structure was refined in the space group P63/m [a = 9.567 (1), c = 20.754 (2) {\AA} and Z = 2] to wR on F of 0.0459. Iodo-oxyapatite has a typical hexagonal apatite structure but the unit cell is tripled along the hexad owing to ordering of the iodide and oxide ions along this direction.",

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year = "1999",

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AU - Henning, Peter Alberius

AU - Lidin, Sven

AU - Petříček, Vačlav

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N2 - Iodo-oxyapatite [pentadecacalcium iodide oxide nonaphosphate, Ca15(PO4)9IO] was synthesized by a flux method and the structure was solved from single-crystal X-ray data. The crystal structure was refined in the space group P63/m [a = 9.567 (1), c = 20.754 (2) Å and Z = 2] to wR on F of 0.0459. Iodo-oxyapatite has a typical hexagonal apatite structure but the unit cell is tripled along the hexad owing to ordering of the iodide and oxide ions along this direction.

AB - Iodo-oxyapatite [pentadecacalcium iodide oxide nonaphosphate, Ca15(PO4)9IO] was synthesized by a flux method and the structure was solved from single-crystal X-ray data. The crystal structure was refined in the space group P63/m [a = 9.567 (1), c = 20.754 (2) Å and Z = 2] to wR on F of 0.0459. Iodo-oxyapatite has a typical hexagonal apatite structure but the unit cell is tripled along the hexad owing to ordering of the iodide and oxide ions along this direction.

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M3 - Article

AN - SCOPUS:0346548727

SN - 0108-7681

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JO - Acta Crystallographica. Section B: Structural Science

JF - Acta Crystallographica. Section B: Structural Science

IS - 2

ER -

Iodo-oxyapatite, the first example from a new class of modulated apatites

Abstract

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