Abstract
Systematic multiconfiguration Hartree-Fock results are presented for the transition probabilities and excited-state lifetimes in the term system of the boron atom. Particularly, the interaction between the 1s(2)2s2p2 configuration and the 1s(2)2s2ns2S and 1s(2)2s2nd2D Rydberg series is considered. Term energies and transition-matrix elements are calculated to convergence using increasing active sets of s, p, d, f, and g orbitals.
Original language | English |
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Pages (from-to) | 3426-3431 |
Journal | Physical Review A (Atomic, Molecular and Optical Physics) |
Volume | 49 |
Issue number | 5 |
DOIs | |
Publication status | Published - 1994 |
Subject classification (UKÄ)
- Atom and Molecular Physics and Optics