Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach

Seetharaman Manojveer; Nitish K. Garg; Zarif Gul; Ayesha Kanwal; Yogesh Goriya; Magnus T. Johnson

doi:10.1002/open.202200245

Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach

Seetharaman Manojveer, Nitish K. Garg, Zarif Gul, Ayesha Kanwal, Yogesh Goriya, Magnus T. Johnson

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.

Original language	English
Article number	e202200245
Journal	ChemistryOpen
Volume	12
Issue number	1
DOIs	https://doi.org/10.1002/open.202200245
Publication status	Published - 2023 Jan

Subject classification (UKÄ)

Organic Chemistry

Free keywords

2-hydroxypyridine
borrowing-hydrogen
catalysis
MLC
α-alkylation

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10.1002/open.202200245Licence: CC BY

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title = "Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach",

abstract = "A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.",

keywords = "2-hydroxypyridine, borrowing-hydrogen, catalysis, MLC, α-alkylation",

author = "Seetharaman Manojveer and Garg, {Nitish K.} and Zarif Gul and Ayesha Kanwal and Yogesh Goriya and Johnson, {Magnus T.}",

year = "2023",

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AU - Manojveer, Seetharaman

AU - Garg, Nitish K.

AU - Gul, Zarif

AU - Kanwal, Ayesha

AU - Goriya, Yogesh

AU - Johnson, Magnus T.

PY - 2023/1

Y1 - 2023/1

N2 - A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.

AB - A new class of palladium complexes bearing bidentate 2-hydroxypyridine based ligands have been prepared and fully characterized. The applications of these new complexes towards ketone alkylation reactions with alcohols through a metal-ligand cooperative borrowing-hydrogen (BH) process were demonstrated.

KW - 2-hydroxypyridine

KW - borrowing-hydrogen

KW - catalysis

KW - MLC

KW - α-alkylation

U2 - 10.1002/open.202200245

DO - 10.1002/open.202200245

M3 - Article

C2 - 36592045

AN - SCOPUS:85145344073

SN - 2191-1363

VL - 12

JO - ChemistryOpen

JF - ChemistryOpen

IS - 1

M1 - e202200245

ER -

Ligand-Promoted [Pd]-Catalyzed α-Alkylation of Ketones through a Borrowing-Hydrogen Approach

Abstract

Subject classification (UKÄ)

Free keywords

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