Luminescence properties of monoclinic Cu4I4(Piperidine)(4)

Ehsan Jalilian; Rong-Zhen Liao; Fahmi Himo; Sven Lidin

doi:10.1016/j.materresbull.2011.04.012

Luminescence properties of monoclinic Cu4I4(Piperidine)(4)

Ehsan Jalilian, Rong-Zhen Liao, Fahmi Himo, Sven Lidin

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1192-1196
Journal	Materials Research Bulletin
Volume	46
Issue number	8
DOIs	https://doi.org/10.1016/j.materresbull.2011.04.012
Publication status	Published - 2011

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)

Subject classification (UKÄ)

Chemical Sciences

Free keywords

Luminescence

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10.1016/j.materresbull.2011.04.012

Single crystal and powder diffractometers
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Centre for Analysis and Synthesis
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title = "Luminescence properties of monoclinic Cu4I4(Piperidine)(4)",

abstract = "A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.",

keywords = "Luminescence",

author = "Ehsan Jalilian and Rong-Zhen Liao and Fahmi Himo and Sven Lidin",

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T1 - Luminescence properties of monoclinic Cu4I4(Piperidine)(4)

AU - Jalilian, Ehsan

AU - Liao, Rong-Zhen

AU - Himo, Fahmi

AU - Lidin, Sven

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Polymer and Materials Chemistry (LTH) (011001041)

PY - 2011

Y1 - 2011

N2 - A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.

AB - A new modification of Cu(4)I(4)Pip(4) has been synthesized under hydrothermal conditions. X-ray crystallography revealed that this compound crystallized in the monoclinic system and consists of a tetrahedral core with composition Cu4I4, in which each Cu atom is coordinated by a piperidine molecule via the N atom. In contrast to a previously reported modification of Cu(4)I(4)Pip(4), the present modification shows luminescent properties when exposed to UV-light. In addition, we have used time-dependent density functional theory calculations to characterize both compounds in term of both absorption and emission. (C) 2011 Elsevier Ltd. All rights reserved.

KW - Luminescence

U2 - 10.1016/j.materresbull.2011.04.012

DO - 10.1016/j.materresbull.2011.04.012

M3 - Article

SN - 0025-5408

VL - 46

SP - 1192

EP - 1196

JO - Materials Research Bulletin

JF - Materials Research Bulletin

IS - 8

ER -

Luminescence properties of monoclinic Cu4I4(Piperidine)(4)

Abstract

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