Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation

Vitor C. Weiss; Giliandro Farias; André L. Amorim; Fernando R. Xavier; Tiago P. Camargo; Mayana B. Bregalda; Matti Haukka; Ebbe Nordlander; Bernardo De Souza; Rosely A. Peralta

doi:10.1021/acs.inorgchem.0c00638

Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation

Vitor C. Weiss, Giliandro Farias, André L. Amorim, Fernando R. Xavier, Tiago P. Camargo, Mayana B. Bregalda, Matti Haukka, Ebbe Nordlander, Bernardo De Souza, Rosely A. Peralta

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

Original language	English
Pages (from-to)	13078-13090
Number of pages	13
Journal	Inorganic Chemistry
Volume	59
Issue number	18
Early online date	2020
DOIs	https://doi.org/10.1021/acs.inorgchem.0c00638
Publication status	Published - 2020

Subject classification (UKÄ)

Inorganic Chemistry

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10.1021/acs.inorgchem.0c00638

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@article{e06282511a044609a25c290e6f0d6bb3,

title = "Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation",

abstract = "The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.",

author = "Weiss, \{Vitor C.\} and Giliandro Farias and Amorim, \{Andr{\'e} L.\} and Xavier, \{Fernando R.\} and Camargo, \{Tiago P.\} and Bregalda, \{Mayana B.\} and Matti Haukka and Ebbe Nordlander and \{De Souza\}, Bernardo and Peralta, \{Rosely A.\}",

year = "2020",

doi = "10.1021/acs.inorgchem.0c00638",

language = "English",

volume = "59",

pages = "13078--13090",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "The American Chemical Society (ACS)",

number = "18",

}

TY - JOUR

T1 - Luminescent PhotoCORMs

T2 - Enabling/Disabling CO Delivery upon Blue Light Irradiation

AU - Weiss, Vitor C.

AU - Farias, Giliandro

AU - Amorim, André L.

AU - Xavier, Fernando R.

AU - Camargo, Tiago P.

AU - Bregalda, Mayana B.

AU - Haukka, Matti

AU - Nordlander, Ebbe

AU - De Souza, Bernardo

AU - Peralta, Rosely A.

PY - 2020

Y1 - 2020

N2 - The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

AB - The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)3Br] (1) and [Mn(Oxa-NMe2)(CO)3Br] (2) were synthesized and fully characterized. Complexes 1 and 2 showed CO release under blue light (λ453). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that 1 and 2 release the Oxa-H and Oxa-NMe2 coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.

UR - https://www.scopus.com/pages/publications/85091324313

U2 - 10.1021/acs.inorgchem.0c00638

DO - 10.1021/acs.inorgchem.0c00638

M3 - Article

C2 - 32902965

AN - SCOPUS:85091324313

SN - 0020-1669

VL - 59

SP - 13078

EP - 13090

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 18

ER -

Luminescent PhotoCORMs: Enabling/Disabling CO Delivery upon Blue Light Irradiation

Abstract

Subject classification (UKÄ)

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