Metal controlled regioselectivity in the cyclometallation of 2-(1-naphthyl)-pyridine.

Mikhail Kondrashov, Sudarkodi Raman, Ola Wendt

Research output: Contribution to journalArticlepeer-review

30 Citations (SciVal)

Abstract

Cyclometallation of 2-(1-naphthyl)-pyridine is described. While cyclopalladation results in a five-membered metallacycle, cycloauration displays a completely orthogonal regioselectivity, resulting in the six-membered ring analogue. Bromination of the gold metallacycle results in the new C-H functionalisation product 2-(8-bromonaphth-1-yl)pyridine.
Original languageEnglish
Pages (from-to)911-913
JournalChemical Communications
Volume51
Issue number5
DOIs
Publication statusPublished - 2015

Subject classification (UKÄ)

  • Chemical Sciences

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