Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

S. V. Zvezdina; O. V. Mal'tseva; N. V. Chizhova; Ivan Scheblykin; N. Zh. Mamardashvili

doi:10.1134/S0036023613040219

Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

S. V. Zvezdina, O. V. Mal'tseva, N. V. Chizhova, Ivan Scheblykin, N. Zh. Mamardashvili

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.

Original language	English
Pages (from-to)	486-490
Journal	Russian Journal of Inorganic Chemistry
Volume	58
Issue number	4
DOIs	https://doi.org/10.1134/S0036023613040219
Publication status	Published - 2013

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

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10.1134/S0036023613040219

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title = "Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide",

abstract = "The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.",

author = "Zvezdina, \{S. V.\} and Mal'tseva, \{O. V.\} and Chizhova, \{N. V.\} and Ivan Scheblykin and Mamardashvili, \{N. Zh.\}",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2013",

doi = "10.1134/S0036023613040219",

language = "English",

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journal = "Russian Journal of Inorganic Chemistry",

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T1 - Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

AU - Zvezdina, S. V.

AU - Mal'tseva, O. V.

AU - Chizhova, N. V.

AU - Scheblykin, Ivan

AU - Mamardashvili, N. Zh.

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2013

Y1 - 2013

N2 - The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.

AB - The metal-exchange reaction of cadmium 5,10,15,20-tetraphenylporphyrinate (CdTPP) and cadmium 2-bromo-5,10,15,20-tetraphenylporphyrinate (CdTPPBr) with copper acetate (Cu(OAc)(2)) in dimethylformamide was studied spectrophotometrically. The kinetic parameters of the metal-exchange reaction were determined. A possible stoichiometric reaction mechanism was proposed.

UR - https://www.scopus.com/pages/publications/84879852457

U2 - 10.1134/S0036023613040219

DO - 10.1134/S0036023613040219

M3 - Article

SN - 0036-0236

VL - 58

SP - 486

EP - 490

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

IS - 4

ER -

Metal-exchange reaction between cadmium tetraphenylporphyrinates and copper(II) in dimethylformamide

Abstract

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