TY - CHAP
T1 - Molecular Movies from Molecular Frame Photoelectron Angular Distribution (MF-PAD) Measurements
AU - Rouzée, Arnaud
AU - Huismans, Ymkje
AU - Kelkensberg, Freek
AU - Smolkowska, Aneta
AU - Jungmann, Julia H.
AU - Gijsbertsen, Arjan
AU - Siu, Wing Kiu
AU - Gademann, Georg
AU - Hundertmark, Axel
AU - Johnsson, Per
AU - Vrakking, Marc J J
PY - 2014/1/1
Y1 - 2014/1/1
N2 - We discuss recent and on-going experiments, where molecular frame photoelectron angular distributions (MFPADs) of high kinetic energy photoelectrons are measured in order to determine the time evolution of molecular structures in the course of a photochemical event. These experiments include, on the one hand, measurements where single XUV/X-ray photons, obtained from a free electron laser (FEL) or by means of high-harmonic generation (HHG), are used to eject a high energy photoelectron, and, on the other hand, measurements where a large number of mid-infrared photons are absorbed in the course of strong-field ionization. In the former case, first results indicate a manifestation of the both the electronic orbital and the molecular structure in the angle-resolved photoelectron distributions, while in the latter case novel holographic structures are measured that suggest that both the molecular structure and ultrafast electronic rearrangement processes can be studied with a time-resolution that reaches down into the attosecond and few-femtosecond domain.
AB - We discuss recent and on-going experiments, where molecular frame photoelectron angular distributions (MFPADs) of high kinetic energy photoelectrons are measured in order to determine the time evolution of molecular structures in the course of a photochemical event. These experiments include, on the one hand, measurements where single XUV/X-ray photons, obtained from a free electron laser (FEL) or by means of high-harmonic generation (HHG), are used to eject a high energy photoelectron, and, on the other hand, measurements where a large number of mid-infrared photons are absorbed in the course of strong-field ionization. In the former case, first results indicate a manifestation of the both the electronic orbital and the molecular structure in the angle-resolved photoelectron distributions, while in the latter case novel holographic structures are measured that suggest that both the molecular structure and ultrafast electronic rearrangement processes can be studied with a time-resolution that reaches down into the attosecond and few-femtosecond domain.
U2 - 10.1007/978-3-319-02051-8_1
DO - 10.1007/978-3-319-02051-8_1
M3 - Book chapter
AN - SCOPUS:84886734519
SN - 9783319020501
T3 - Springer Series in Chemical Physics
SP - 1
EP - 24
BT - Ultrafast Phenomena in Molecular Sciences
ER -