TY - JOUR
T1 - Nature of the bias-dependent symmetry reduction of iron phthalocyanine on Cu(111)
AU - Snezhkova, Olesia
AU - Lueder, Johann
AU - Wiengarten, Alissa
AU - Burema, Shiri R.
AU - Bischoff, Felix
AU - He, Yuanqin
AU - Rusz, Jan
AU - Knudsen, Jan
AU - Bocquet, Marie-Laure
AU - Seufert, Knud
AU - Barth, Johannes V.
AU - Auwaerter, Willi
AU - Brena, Barbara
AU - Schnadt, Joachim
PY - 2015
Y1 - 2015
N2 - Subtle changes in the geometric and electronic properties of supported molecules, with a potential impact on the functioning of molecular devices, can typically be imaged by scanning probe microscopy, but their exact origin and nature often remain unclear. Here we show explicitly that the symmetry reduction of iron phthalocyanine upon adsorption on Cu(111) can be observed not only in scanning tunneling microscopy, but also in core-level spectroscopy, and that it is related to nonisotropic charge transfer into the two principal molecular axes, but in combination with topographic influences.
AB - Subtle changes in the geometric and electronic properties of supported molecules, with a potential impact on the functioning of molecular devices, can typically be imaged by scanning probe microscopy, but their exact origin and nature often remain unclear. Here we show explicitly that the symmetry reduction of iron phthalocyanine upon adsorption on Cu(111) can be observed not only in scanning tunneling microscopy, but also in core-level spectroscopy, and that it is related to nonisotropic charge transfer into the two principal molecular axes, but in combination with topographic influences.
U2 - 10.1103/PhysRevB.92.075428
DO - 10.1103/PhysRevB.92.075428
M3 - Article
SN - 1098-0121
VL - 92
JO - Physical Review B (Condensed Matter and Materials Physics)
JF - Physical Review B (Condensed Matter and Materials Physics)
IS - 7
M1 - 075428
ER -