Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111)

Catherine M. Doyle; John P. Cunniffe; Sergey A. Krasnikov; Alexei Preobrajenski; Zheshen Li; Natalia N. Sergeeva; Mathias O. Senge; Attilio A. Cafolla

doi:10.1039/c3cc48913b

Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111)

Catherine M. Doyle, John P. Cunniffe, Sergey A. Krasnikov, Alexei Preobrajenski, Zheshen Li, Natalia N. Sergeeva, Mathias O. Senge, Attilio A. Cafolla

MAX IV Laboratory

Research output: Contribution to journal › Article › peer-review

Abstract

A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis-(4-bromophenyl) porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions

Original language	English
Pages (from-to)	3447-3449
Journal	Chemical Communications
Volume	50
Issue number	26
DOIs	https://doi.org/10.1039/c3cc48913b
Publication status	Published - 2014

Subject classification (UKÄ)

Chemical Sciences

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10.1039/c3cc48913b

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@article{ea42728d4cda460cb49e8369b099943c,

title = "Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111)",

abstract = "A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis-(4-bromophenyl) porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions",

author = "Doyle, {Catherine M.} and Cunniffe, {John P.} and Krasnikov, {Sergey A.} and Alexei Preobrajenski and Zheshen Li and Sergeeva, {Natalia N.} and Senge, {Mathias O.} and Cafolla, {Attilio A.}",

year = "2014",

doi = "10.1039/c3cc48913b",

language = "English",

volume = "50",

pages = "3447--3449",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "26",

}

TY - JOUR

T1 - Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111)

AU - Doyle, Catherine M.

AU - Cunniffe, John P.

AU - Krasnikov, Sergey A.

AU - Preobrajenski, Alexei

AU - Li, Zheshen

AU - Sergeeva, Natalia N.

AU - Senge, Mathias O.

AU - Cafolla, Attilio A.

PY - 2014

Y1 - 2014

N2 - A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis-(4-bromophenyl) porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions

AB - A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis-(4-bromophenyl) porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions

U2 - 10.1039/c3cc48913b

DO - 10.1039/c3cc48913b

M3 - Article

C2 - 24548915

SN - 1364-548X

VL - 50

SP - 3447

EP - 3449

JO - Chemical Communications

JF - Chemical Communications

IS - 26

ER -

Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111)

Abstract

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