On-surface photo-dissociation of C-Br bonds: towards room temperature Ullmann coupling

Andrea Basagni; Lara Ferrighi; Mattia Cattelan; Louis Nicolas; Karsten Handrup; Luca Vaghi; Antonio Papagni; Francesco Sedona; Cristiana Di Valentin; Stefano Agnoli; Mauro Sambi

doi:10.1039/c5cc04317d

On-surface photo-dissociation of C-Br bonds: towards room temperature Ullmann coupling

Andrea Basagni, Lara Ferrighi, Mattia Cattelan, Louis Nicolas, Karsten Handrup, Luca Vaghi, Antonio Papagni, Francesco Sedona, Cristiana Di Valentin, Stefano Agnoli, Mauro Sambi

MAX IV Laboratory

Research output: Contribution to journal › Article › peer-review

Abstract

The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo-and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.

Original language	English
Pages (from-to)	12593-12596
Journal	Chemical Communications
Volume	51
Issue number	63
DOIs	https://doi.org/10.1039/c5cc04317d
Publication status	Published - 2015

Subject classification (UKÄ)

Chemical Sciences

Access to Document

10.1039/c5cc04317d

Cite this

@article{5d175844fdb9412f86b1c7953a491a10,

title = "On-surface photo-dissociation of C-Br bonds: towards room temperature Ullmann coupling",

abstract = "The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo-and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.",

author = "Andrea Basagni and Lara Ferrighi and Mattia Cattelan and Louis Nicolas and Karsten Handrup and Luca Vaghi and Antonio Papagni and Francesco Sedona and {Di Valentin}, Cristiana and Stefano Agnoli and Mauro Sambi",

year = "2015",

doi = "10.1039/c5cc04317d",

language = "English",

volume = "51",

pages = "12593--12596",

journal = "Chemical Communications",

issn = "1364-548X",

publisher = "Royal Society of Chemistry",

number = "63",

}

TY - JOUR

T1 - On-surface photo-dissociation of C-Br bonds: towards room temperature Ullmann coupling

AU - Basagni, Andrea

AU - Ferrighi, Lara

AU - Cattelan, Mattia

AU - Nicolas, Louis

AU - Handrup, Karsten

AU - Vaghi, Luca

AU - Papagni, Antonio

AU - Sedona, Francesco

AU - Di Valentin, Cristiana

AU - Agnoli, Stefano

AU - Sambi, Mauro

PY - 2015

Y1 - 2015

N2 - The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo-and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.

AB - The surface-assisted synthesis of gold-organometallic hybrids on the Au(111) surface both by thermo-and light-initiated dehalogenation of bromo-substituted tetracene is reported. Combined X-ray photoemission (XPS) and scanning tunneling microscopy (STM) data reveal a significant increase of the surface order when mild reaction conditions are combined with 405 nm light irradiation.

U2 - 10.1039/c5cc04317d

DO - 10.1039/c5cc04317d

M3 - Article

C2 - 26154619

SN - 1364-548X

VL - 51

SP - 12593

EP - 12596

JO - Chemical Communications

JF - Chemical Communications

IS - 63

ER -

On-surface photo-dissociation of C-Br bonds: towards room temperature Ullmann coupling

Abstract

Subject classification (UKÄ)

Access to Document

Fingerprint

Cite this