Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

A Behrens, U Behrens, Ebbe Nordlander, C Bader, D Rehder

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5 Citations (SciVal)

Abstract

Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.
Original languageEnglish
Pages (from-to)1970-1974
JournalInorganica Chimica Acta
Volume358
Issue number6
DOIs
Publication statusPublished - 2005

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

  • Atom and Molecular Physics and Optics

Keywords

  • molybdopterin
  • molybdenum complexes
  • thiofunctional ligands
  • oxotransferases

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