Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

A Behrens; U Behrens; Ebbe Nordlander; C Bader; D Rehder

doi:10.1016/j.ica.2004.12.039

Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

A Behrens, U Behrens, Ebbe Nordlander, C Bader, D Rehder

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.

Original language	English
Pages (from-to)	1970-1974
Journal	Inorganica Chimica Acta
Volume	358
Issue number	6
DOIs	https://doi.org/10.1016/j.ica.2004.12.039
Publication status	Published - 2005

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

molybdopterin
molybdenum complexes
thiofunctional ligands
oxotransferases

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10.1016/j.ica.2004.12.039

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title = "Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands",

abstract = "Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17)\{MoO\}(8)center dot 10thf center dot hexane, where \{MoO\}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [\{(MoO)-O-IV(S'(2))\} \{(MoO)-O-V(S'(2))\}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.",

keywords = "molybdopterin, molybdenum complexes, thiofunctional ligands, oxotransferases",

author = "A Behrens and U Behrens and Ebbe Nordlander and C Bader and D Rehder",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2005",

doi = "10.1016/j.ica.2004.12.039",

language = "English",

volume = "358",

pages = "1970--1974",

journal = "Inorganica Chimica Acta",

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TY - JOUR

T1 - Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

AU - Behrens, A

AU - Behrens, U

AU - Nordlander, Ebbe

AU - Bader, C

AU - Rehder, D

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2005

Y1 - 2005

N2 - Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.

AB - Reaction of [MoO2(acac)(2)] with Li2NS2S'(2), (S is a thioether, S' a thiophenolate function) yielded the compound Li-7(thf)(17){MoO}(8)center dot 10thf center dot hexane, where {MoO}(8) represents one [(MoO)-O-IV(NS2S'(2))] 1, three [(MoO)-O-III(NS2S'(2))](-) (2, linked, via the oxo group, to [Li(thf)3](+)) and two [(MoO)-O-V(S'(2))(2)](2-)(2) .A mixed-valent variant of 3, [{(MoO)-O-IV(S'(2))} {(MoO)-O-V(S'(2))}](-) (3b, with an additional [Li(thf)3](+) attached to S'), was also identified. The compounds model features pertinent to oxo-transferases containing the molybdopterin cofactor.

KW - molybdopterin

KW - molybdenum complexes

KW - thiofunctional ligands

KW - oxotransferases

UR - https://www.scopus.com/pages/publications/14844298767

U2 - 10.1016/j.ica.2004.12.039

DO - 10.1016/j.ica.2004.12.039

M3 - Article

SN - 0020-1693

VL - 358

SP - 1970

EP - 1974

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 6

ER -

Oxomolybdenum(III, IV and V) complexes of thiofunctional ligands

Abstract

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