Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution

Vadim Yu. Kukushkin; Karin Lövqvist; Bertil Noren; Åke Oskarsson; Lars Ivar Elding

doi:10.1080/10426509308037400

Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution

Vadim Yu. Kukushkin, Karin Lövqvist, Bertil Noren, Åke Oskarsson, Lars Ivar Elding

Centre for Analysis and Synthesis

Lund University

Research output: Contribution to journal › Article › peer-review

Abstract

Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.

Original language	English
Pages (from-to)	253-255
Number of pages	3
Journal	Phosphorus, Sulfur, and Silicon and the Related Elements
Volume	75
Issue number	1-4
DOIs	https://doi.org/10.1080/10426509308037400
Publication status	Published - 1993

Subject classification (UKÄ)

Inorganic Chemistry

Free keywords

Platinum(II)
Thioether complex
Phenyl abstraction
Tetraphenyl borate
Synthesis
X-ray diffraction

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10.1080/10426509308037400

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@article{fc7dda572883419fbe7fb71ed8d0eac5,

title = "Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution",

abstract = "Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.",

keywords = "Platinum(II) complexes, Thioethers, Tetraphenylborate, Phenylation , Preparation, Platinum(II), Thioether complex, Phenyl abstraction, Tetraphenyl borate, Synthesis, X-ray diffraction",

author = "Kukushkin, {Vadim Yu.} and Karin L{\"o}vqvist and Bertil Noren and {\AA}ke Oskarsson and Elding, {Lars Ivar}",

year = "1993",

doi = "10.1080/10426509308037400",

language = "English",

volume = "75",

pages = "253--255",

journal = "Phosphorus, Sulfur, and Silicon and the Related Elements",

issn = "1042-6507",

publisher = "Taylor & Francis",

number = "1-4",

}

TY - JOUR

T1 - Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution

AU - Kukushkin, Vadim Yu.

AU - Lövqvist, Karin

AU - Noren, Bertil

AU - Oskarsson, Åke

AU - Elding, Lars Ivar

PY - 1993

Y1 - 1993

N2 - Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.

AB - Platinum(II) complexes of the type [Pt(thioether)2Cl]+(thioether = dimethyl sulfide, thioxane) are capable of abstracting a phenyl group from the BPh4 counterion with formation of trans[Pt(thioether)2ClPh] compounds. Thermal reactions proceed both in the solid phase and in nitromethane solution at elevated temperature and have preparative importance. Phenylation of the Pt(II) centre also occurs in reaction between [Pt(Me2S)2Cl2] and AgBPh4 in CH2Cl2 suspension. Brief X-ray crystallographic structural data for trans-[Pt(Me2S)2ClPh] and [Pt(thioether)3Cl]X (thioether = Me2S, tx, X = SO3CF3; thioether = Me2S, X = PF6) are reported.

KW - Platinum(II) complexes

KW - Thioethers

KW - Tetraphenylborate

KW - Phenylation

KW - Preparation

KW - Platinum(II)

KW - Thioether complex

KW - Phenyl abstraction

KW - Tetraphenyl borate

KW - Synthesis

KW - X-ray diffraction

U2 - 10.1080/10426509308037400

DO - 10.1080/10426509308037400

M3 - Article

SN - 1042-6507

VL - 75

SP - 253

EP - 255

JO - Phosphorus, Sulfur, and Silicon and the Related Elements

JF - Phosphorus, Sulfur, and Silicon and the Related Elements

IS - 1-4

ER -

Phenylation of Platinum(II) Thioether Complexes by Tetraphenylborate(III) in Solid State and Nitromethane Solution

Abstract

Subject classification (UKÄ)

Free keywords

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