Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

Anders Thapper; Emma Sparr; Brian F G Johnson; Jack Lewis; Paul R Raithby; Ebbe Nordlander

doi:10.1016/j.inoche.2003.12.032

Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

Anders Thapper, Emma Sparr, Brian F G Johnson, Jack Lewis, Paul R Raithby, Ebbe Nordlander

Research output: Contribution to journal › Article › peer-review

Abstract

The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].

Original language	English
Pages (from-to)	443-446
Journal	Inorganic Chemistry Communications
Volume	7
Issue number	3
DOIs	https://doi.org/10.1016/j.inoche.2003.12.032
Publication status	Published - 2004

Subject classification (UKÄ)

Physical Chemistry (including Surface- and Colloid Chemistry)

Free keywords

Cluster
Hemilabile ligand
Allylphosphine

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10.1016/j.inoche.2003.12.032

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@article{fac8d7278ca74c7789163cfd8477fcbe,

title = "Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster",

abstract = "The triallylphosphine-substituted clusters [Ru3(CO)11\{P(CH2CH=CH2)3\}], [Ru3(CO)10\{P(CH2CH=CH2)3\}2] and [Ru3(CO)10\{;-CH2=CHCH2P(CH2CH=CH2)2\}] have been prepared; reaction of [Ru3(CO)10\{;-CH2=CHCH2P(CH2CH=CH2)2\}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11\{P(CH2CH=CH2)3\}(PR3)].",

keywords = "Cluster, Hemilabile ligand, Allylphosphine",

author = "Anders Thapper and Emma Sparr and Johnson, \{Brian F G\} and Jack Lewis and Raithby, \{Paul R\} and Ebbe Nordlander",

year = "2004",

doi = "10.1016/j.inoche.2003.12.032",

language = "English",

volume = "7",

pages = "443--446",

journal = "Inorganic Chemistry Communications",

issn = "1879-0259",

publisher = "Elsevier",

number = "3",

}

TY - JOUR

T1 - Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

AU - Thapper, Anders

AU - Sparr, Emma

AU - Johnson, Brian F G

AU - Lewis, Jack

AU - Raithby, Paul R

AU - Nordlander, Ebbe

PY - 2004

Y1 - 2004

N2 - The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].

AB - The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CH=CH2)3}], [Ru3(CO)10{P(CH2CH=CH2)3}2] and [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] have been prepared; reaction of [Ru3(CO)10{;-CH2=CHCH2P(CH2CH=CH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl -bond and formation of [Ru3(CO)11{P(CH2CH=CH2)3}(PR3)].

KW - Cluster

KW - Hemilabile ligand

KW - Allylphosphine

UR - https://www.scopus.com/pages/publications/1242351272

U2 - 10.1016/j.inoche.2003.12.032

DO - 10.1016/j.inoche.2003.12.032

M3 - Article

SN - 1879-0259

VL - 7

SP - 443

EP - 446

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 3

ER -

Reversible -coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

Abstract

Subject classification (UKÄ)

Free keywords

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