Rheological and rheo-SALS investigation of the multi-lamellar vesicle formation in the C12E3/D2O system

Luigi Gentile; Cesare Oliviero Rossi; Ulf Olsson

doi:10.1016/j.jcis.2011.10.057

Rheological and rheo-SALS investigation of the multi-lamellar vesicle formation in the C12E3/D2O system

Luigi Gentile, Cesare Oliviero Rossi, Ulf Olsson

Physical Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Usually in nonionic surfactant aqueous systems of the CnEm type, a lamellar phase occurs over a wide temperature and concentration range. For some CnEm surfactants, multi-lamellar vesicle (MLV) formation has been observed when the lamellar phase is subjected to shear flow. This communication reports the shear flow behavior at different shear rate values of a CnEm (where "n" is 12 and "m" is 3) aqueous system at 34 degrees C. The typical transient viscosity behavior of the shear-induced MLV formation in C12E3/D2O at 50 wt% of surfactant has been observed. The MLV formation is confirmed by time-resolved rheo-small angle light scattering (SALS) experiments. The experimental data show an intermediate structure that has been attributed to a multi-lamellar cylinders (MLCs). (C) 2011 Elsevier Inc. All rights reserved.

Original language	English
Pages (from-to)	537-539
Journal	Journal of Colloid and Interface Science
Volume	367
DOIs	https://doi.org/10.1016/j.jcis.2011.10.057
Publication status	Published - 2012

Subject classification (UKÄ)

Physical Chemistry

Free keywords

Rheology
Rheo-SALS
MLV formation
Onions
CnEm

Access to Document

10.1016/j.jcis.2011.10.057

Cite this

@article{f8cb97495b974c60a8ea02f27a61b779,

title = "Rheological and rheo-SALS investigation of the multi-lamellar vesicle formation in the C12E3/D2O system",

abstract = "Usually in nonionic surfactant aqueous systems of the CnEm type, a lamellar phase occurs over a wide temperature and concentration range. For some CnEm surfactants, multi-lamellar vesicle (MLV) formation has been observed when the lamellar phase is subjected to shear flow. This communication reports the shear flow behavior at different shear rate values of a CnEm (where {"}n{"} is 12 and {"}m{"} is 3) aqueous system at 34 degrees C. The typical transient viscosity behavior of the shear-induced MLV formation in C12E3/D2O at 50 wt% of surfactant has been observed. The MLV formation is confirmed by time-resolved rheo-small angle light scattering (SALS) experiments. The experimental data show an intermediate structure that has been attributed to a multi-lamellar cylinders (MLCs). (C) 2011 Elsevier Inc. All rights reserved.",

keywords = "Rheology, Rheo-SALS, MLV formation, Onions, CnEm",

author = "Luigi Gentile and Rossi, {Cesare Oliviero} and Ulf Olsson",

year = "2012",

doi = "10.1016/j.jcis.2011.10.057",

language = "English",

volume = "367",

pages = "537--539",

journal = "Journal of Colloid and Interface Science",

issn = "1095-7103",

publisher = "Elsevier",

}

TY - JOUR

T1 - Rheological and rheo-SALS investigation of the multi-lamellar vesicle formation in the C12E3/D2O system

AU - Gentile, Luigi

AU - Rossi, Cesare Oliviero

AU - Olsson, Ulf

PY - 2012

Y1 - 2012

N2 - Usually in nonionic surfactant aqueous systems of the CnEm type, a lamellar phase occurs over a wide temperature and concentration range. For some CnEm surfactants, multi-lamellar vesicle (MLV) formation has been observed when the lamellar phase is subjected to shear flow. This communication reports the shear flow behavior at different shear rate values of a CnEm (where "n" is 12 and "m" is 3) aqueous system at 34 degrees C. The typical transient viscosity behavior of the shear-induced MLV formation in C12E3/D2O at 50 wt% of surfactant has been observed. The MLV formation is confirmed by time-resolved rheo-small angle light scattering (SALS) experiments. The experimental data show an intermediate structure that has been attributed to a multi-lamellar cylinders (MLCs). (C) 2011 Elsevier Inc. All rights reserved.

AB - Usually in nonionic surfactant aqueous systems of the CnEm type, a lamellar phase occurs over a wide temperature and concentration range. For some CnEm surfactants, multi-lamellar vesicle (MLV) formation has been observed when the lamellar phase is subjected to shear flow. This communication reports the shear flow behavior at different shear rate values of a CnEm (where "n" is 12 and "m" is 3) aqueous system at 34 degrees C. The typical transient viscosity behavior of the shear-induced MLV formation in C12E3/D2O at 50 wt% of surfactant has been observed. The MLV formation is confirmed by time-resolved rheo-small angle light scattering (SALS) experiments. The experimental data show an intermediate structure that has been attributed to a multi-lamellar cylinders (MLCs). (C) 2011 Elsevier Inc. All rights reserved.

KW - Rheology

KW - Rheo-SALS

KW - MLV formation

KW - Onions

KW - CnEm

U2 - 10.1016/j.jcis.2011.10.057

DO - 10.1016/j.jcis.2011.10.057

M3 - Article

C2 - 22104279

SN - 1095-7103

VL - 367

SP - 537

EP - 539

JO - Journal of Colloid and Interface Science

JF - Journal of Colloid and Interface Science

ER -

Rheological and rheo-SALS investigation of the multi-lamellar vesicle formation in the C12E3/D2O system

Abstract

Subject classification (UKÄ)

Free keywords

Access to Document

Fingerprint

Cite this