Ru-Catalyzed Completely Deoxygenative Coupling of 2-Arylethanols through Base-Induced Net Decarbonylation

Seetharaman Manojveer, Sebastian J.K. Forrest, Magnus T. Johnson

Research output: Contribution to journalArticlepeer-review

Abstract

Substituted arylethanols can be coupled by using a readily available Ru catalyst in a fully deoxygenative manner to produce hydrocarbon chains in one step. Control experiments indicate that the first deoxygenation occurs through an aldol condensation, whereas the second occurs through a base-induced net decarbonylation. This double deoxygenation enables further development in the use of alcohols as versatile and green alkylating reagents, as well as in other fields, such as deoxygenation and upgrading of overfunctionalized biomass to produce hydrocarbons.

Original languageEnglish
Pages (from-to)803-807
Number of pages5
JournalChemistry - A European Journal
Volume24
Issue number4
DOIs
Publication statusPublished - 2018 Jan 19

Subject classification (UKÄ)

  • Biocatalysis and Enzyme Technology

Free keywords

  • decarbonylation
  • dehydrogenation
  • hydrogen-borrowing catalysis
  • metal hydrides
  • ruthenium

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