Selective isomerization of 1-alkenes by binary metal carbonyl compounds

Akella Sivaramakrishna; Paul Mushonga; Ian L Rogers; Feng Zheng; Raymond J Haines; Ebbe Nordlander; John R Moss

doi:10.1016/j.poly.2008.02.026

Selective isomerization of 1-alkenes by binary metal carbonyl compounds

Akella Sivaramakrishna, Paul Mushonga, Ian L Rogers, Feng Zheng, Raymond J Haines, Ebbe Nordlander, John R Moss

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient and selective isomerization of 1-alkenes to their corresponding 2-alkenes is achieved by using binary metal carbonyls such as Ru-3(CO)(12) as catalysts. Possible mechanisms are discussed. Substituents on the 1-alkene have a significant effect on the isomerization. (C) 2008 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	1911-1916
Journal	Polyhedron
Volume	27
Issue number	7
DOIs	https://doi.org/10.1016/j.poly.2008.02.026
Publication status	Published - 2008

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

substituent effects
clusters
metal carbonyls
isomerization
1-alkenes

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10.1016/j.poly.2008.02.026

Cite this

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title = "Selective isomerization of 1-alkenes by binary metal carbonyl compounds",

abstract = "An efficient and selective isomerization of 1-alkenes to their corresponding 2-alkenes is achieved by using binary metal carbonyls such as Ru-3(CO)(12) as catalysts. Possible mechanisms are discussed. Substituents on the 1-alkene have a significant effect on the isomerization. (C) 2008 Elsevier Ltd. All rights reserved.",

keywords = "substituent effects, clusters, metal carbonyls, isomerization, 1-alkenes",

author = "Akella Sivaramakrishna and Paul Mushonga and Rogers, \{Ian L\} and Feng Zheng and Haines, \{Raymond J\} and Ebbe Nordlander and Moss, \{John R\}",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2008",

doi = "10.1016/j.poly.2008.02.026",

language = "English",

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pages = "1911--1916",

journal = "Polyhedron",

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T1 - Selective isomerization of 1-alkenes by binary metal carbonyl compounds

AU - Sivaramakrishna, Akella

AU - Mushonga, Paul

AU - Rogers, Ian L

AU - Zheng, Feng

AU - Haines, Raymond J

AU - Nordlander, Ebbe

AU - Moss, John R

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2008

Y1 - 2008

N2 - An efficient and selective isomerization of 1-alkenes to their corresponding 2-alkenes is achieved by using binary metal carbonyls such as Ru-3(CO)(12) as catalysts. Possible mechanisms are discussed. Substituents on the 1-alkene have a significant effect on the isomerization. (C) 2008 Elsevier Ltd. All rights reserved.

AB - An efficient and selective isomerization of 1-alkenes to their corresponding 2-alkenes is achieved by using binary metal carbonyls such as Ru-3(CO)(12) as catalysts. Possible mechanisms are discussed. Substituents on the 1-alkene have a significant effect on the isomerization. (C) 2008 Elsevier Ltd. All rights reserved.

KW - substituent effects

KW - clusters

KW - metal carbonyls

KW - isomerization

KW - 1-alkenes

UR - https://www.scopus.com/pages/publications/42649130389

U2 - 10.1016/j.poly.2008.02.026

DO - 10.1016/j.poly.2008.02.026

M3 - Article

SN - 0277-5387

VL - 27

SP - 1911

EP - 1916

JO - Polyhedron

JF - Polyhedron

IS - 7

ER -

Selective isomerization of 1-alkenes by binary metal carbonyl compounds

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

Access to Document

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