Sensor and biosensor based on Prussian Blue modified gold and platinum screen printed electrodes

I L de Mattos; Lo Gorton; Tautgirdas Ruzgas

doi:10.1016/S0956-5663(02)00185-9

Sensor and biosensor based on Prussian Blue modified gold and platinum screen printed electrodes

I L de Mattos, Lo Gorton, Tautgirdas Ruzgas

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

Gold (Au) and platinum (Pt) screen-printed electrodes were modified with Prussian Blue (PB) for the development of amperometric sensors selective for hydrogen peroxide detection. The sensors exhibited sensitivities towards H2O2 equal to 2 A M−1 cm−2 for Au and 1 A M−1 cm−2 for Pt electrodes. The sensors were also employed as the basis for construction of glucose biosensors through further modification with crystallised glucose oxidase immobilised in a Nafion membrane. In order to improve the operational stability of the modified electrodes a buffer solution containing tetrabutylammonium toluene-4-sulfonate was used. The long-term performance of the sensors and biosensors were evaluated by continuous monitoring of hydrogen peroxide and glucose solutions (50 M and 1 mM, respectively) in the flow-injection mode for 10 h.

Original language	English
Pages (from-to)	193-200
Journal	Biosensors & Bioelectronics
Volume	18
Issue number	2-3
DOIs	https://doi.org/10.1016/S0956-5663(02)00185-9
Publication status	Published - 2003

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Analytical Chemistry (S/LTH) (011001004)

Subject classification (UKÄ)

Analytical Chemistry

Keywords

Screen-printed electrodes
Prussian Blue
Biosensor
Amperometric sensor

Access to Document

10.1016/S0956-5663(02)00185-9

Cite this

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title = "Sensor and biosensor based on Prussian Blue modified gold and platinum screen printed electrodes",

abstract = "Gold (Au) and platinum (Pt) screen-printed electrodes were modified with Prussian Blue (PB) for the development of amperometric sensors selective for hydrogen peroxide detection. The sensors exhibited sensitivities towards H2O2 equal to 2 A M−1 cm−2 for Au and 1 A M−1 cm−2 for Pt electrodes. The sensors were also employed as the basis for construction of glucose biosensors through further modification with crystallised glucose oxidase immobilised in a Nafion membrane. In order to improve the operational stability of the modified electrodes a buffer solution containing tetrabutylammonium toluene-4-sulfonate was used. The long-term performance of the sensors and biosensors were evaluated by continuous monitoring of hydrogen peroxide and glucose solutions (50 M and 1 mM, respectively) in the flow-injection mode for 10 h.",

keywords = "Screen-printed electrodes, Prussian Blue, Biosensor, Amperometric sensor",

author = "{de Mattos}, {I L} and Lo Gorton and Tautgirdas Ruzgas",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Analytical Chemistry (S/LTH) (011001004)",

year = "2003",

doi = "10.1016/S0956-5663(02)00185-9",

language = "English",

volume = "18",

pages = "193--200",

journal = "Biosensors and Bioelectronics",

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T1 - Sensor and biosensor based on Prussian Blue modified gold and platinum screen printed electrodes

AU - de Mattos, I L

AU - Gorton, Lo

AU - Ruzgas, Tautgirdas

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Analytical Chemistry (S/LTH) (011001004)

PY - 2003

Y1 - 2003

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AB - Gold (Au) and platinum (Pt) screen-printed electrodes were modified with Prussian Blue (PB) for the development of amperometric sensors selective for hydrogen peroxide detection. The sensors exhibited sensitivities towards H2O2 equal to 2 A M−1 cm−2 for Au and 1 A M−1 cm−2 for Pt electrodes. The sensors were also employed as the basis for construction of glucose biosensors through further modification with crystallised glucose oxidase immobilised in a Nafion membrane. In order to improve the operational stability of the modified electrodes a buffer solution containing tetrabutylammonium toluene-4-sulfonate was used. The long-term performance of the sensors and biosensors were evaluated by continuous monitoring of hydrogen peroxide and glucose solutions (50 M and 1 mM, respectively) in the flow-injection mode for 10 h.

KW - Screen-printed electrodes

KW - Prussian Blue

KW - Biosensor

KW - Amperometric sensor

U2 - 10.1016/S0956-5663(02)00185-9

DO - 10.1016/S0956-5663(02)00185-9

M3 - Article

SN - 0956-5663

VL - 18

SP - 193

EP - 200

JO - Biosensors and Bioelectronics

JF - Biosensors and Bioelectronics

IS - 2-3

ER -

Sensor and biosensor based on Prussian Blue modified gold and platinum screen printed electrodes

Abstract

Bibliographical note

Subject classification (UKÄ)

Keywords

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