Solution and structural studies of the Cd(II) - Aconitate system

George Kostakis; Gerasimos Malandrinos; Ebbe Nordlander; Matti Haukka; John C. Plakatouras

doi:10.1016/j.poly.2009.05.008

Solution and structural studies of the Cd(II) - Aconitate system

George Kostakis, Gerasimos Malandrinos, Ebbe Nordlander, Matti Haukka, John C. Plakatouras

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.

Original language	English
Pages (from-to)	3227-3234
Journal	Polyhedron
Volume	28
Issue number	15
DOIs	https://doi.org/10.1016/j.poly.2009.05.008
Publication status	Published - 2009

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

Topology
Coordination polymers
Lewis base
Potentiometry
Cadmium complexes

Access to Document

10.1016/j.poly.2009.05.008

Cite this

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title = "Solution and structural studies of the Cd(II) - Aconitate system",

abstract = "The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.",

keywords = "Topology, Coordination polymers, Lewis base, Potentiometry, Cadmium complexes",

author = "George Kostakis and Gerasimos Malandrinos and Ebbe Nordlander and Matti Haukka and Plakatouras, \{John C.\}",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2009",

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AU - Kostakis, George

AU - Malandrinos, Gerasimos

AU - Nordlander, Ebbe

AU - Haukka, Matti

AU - Plakatouras, John C.

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2009

Y1 - 2009

N2 - The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.

AB - The complexing ability of the binary system trans-aconitic acid (H3L) with regard to Cd(II) and the crystal structures of the binary system Cd(II)-(H3L), [Cd3L2(H2O)(6)] n(1) and ternary systems of Cd(II)-(H3L)-Lewis base [Lewis base = 1,10-phenanthroline (2) and 2,2'-bipyridine (3)] have been determined. Compound I is a rare binodal four-connected three-dimensional (3D) metal-organic framework possessing a moganite (mog) topology. Compounds 2 and 3 represent infinite one-dimensional (1D) chains forming three-dimensional metal-supramolecular structures through H-bond and pi-pi stacking interactions. All compounds have been characterized by spectroscopic and thermogravimetric techniques. (C) 2009 Elsevier Ltd. All rights reserved.

KW - Topology

KW - Coordination polymers

KW - Lewis base

KW - Potentiometry

KW - Cadmium complexes

UR - https://www.scopus.com/pages/publications/70349448546

U2 - 10.1016/j.poly.2009.05.008

DO - 10.1016/j.poly.2009.05.008

M3 - Article

SN - 0277-5387

VL - 28

SP - 3227

EP - 3234

JO - Polyhedron

JF - Polyhedron

IS - 15

ER -

Solution and structural studies of the Cd(II) - Aconitate system

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

Access to Document

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Cite this