Superheavy Element Flerovium (Element 114) Is a Volatile Metal

A. Yakushev; J.M. Gates; A. Türler; M. Schädel; C.E. Düllmann; D. Ackermann; L.-L. Andersson; M. Block; W. Brüchle; J. Dvorak; K. Eberhardt; H.G. Essel; J. Even; Ulrika Forsberg; A. Gorshkov; R. Graeger; K.E. Gregorich; W. Hartmann; R.-D. Herzberg; F.P. Heßberger; D. Hild; A. Hübner; E. Jäger; J. Khuyagbaatar; B. Kindler; J.V. Kratz; J. Krier; N. Kurz; B. Lommel; L.J. Niewisch; H. Nitsche; J.P. Omtvedt; E. Parr; Z. Qin; Dirk Rudolph; J. Runke; B. Schausten; E. Schimpf; A. Semchenkov; J. Steiner; P. Thörle-Pospiech; J. Uusitalo; M. Wegrzecki; N. Wiehl

doi:10.1021/ic4026766

Superheavy Element Flerovium (Element 114) Is a Volatile Metal

A. Yakushev, J.M. Gates, A. Türler, M. Schädel, C.E. Düllmann, D. Ackermann, L.-L. Andersson, M. Block, W. Brüchle, J. Dvorak, K. Eberhardt, H.G. Essel, J. Even, Ulrika Forsberg, A. Gorshkov, R. Graeger, K.E. Gregorich, W. Hartmann, R.-D. Herzberg, F.P. HeßbergerD. Hild, A. Hübner, E. Jäger, J. Khuyagbaatar, B. Kindler, J.V. Kratz, J. Krier, N. Kurz, B. Lommel, L.J. Niewisch, H. Nitsche, J.P. Omtvedt, E. Parr, Z. Qin, Dirk Rudolph, J. Runke, B. Schausten, E. Schimpf, A. Semchenkov, J. Steiner, P. Thörle-Pospiech, J. Uusitalo, M. Wegrzecki, N. Wiehl

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Abstract

The electronic structure of superheavy elements (Z ≥ 104) and their chemical properties are dominated by relativistic effects. Recently two superheavy elements were recognized by the IUPAC and named flerovium (Fl, Z = 114) and livermorium (Lv, Z = 116). Fl is the heaviest element with which chemical experiments were performed. Here, we report on experiments that help answering the long-standing question whether Fl behaves rather like a noble gas or like a metal.

Original language	English
Pages (from-to)	1624-1629
Number of pages	6
Journal	Inorganic Chemistry
Volume	53
Issue number	3
DOIs	https://doi.org/10.1021/ic4026766
Publication status	Published - 2014

Subject classification (UKÄ)

Subatomic Physics

Free keywords

superheavy elements
element 114
gas chemistry

Access to Document

10.1021/ic4026766

LUP_E114_Chemistry

7 Article

Manifestation of relativistic effects in the chemical properties of nihonium and moscovium revealed by gas chromatography studies
Yakushev, A., Khuyagbaatar, J., Düllmann, C. E., Block, M., Cantemir, R. A., Cox, D. M., Dietzel, D., Giacoppo, F., Hrabar, Y., Iliaš, M., Jäger, E., Krier, J., Krupp, D., Kurz, N., Lens, L., Löchner, S., Mokry, C., Mošať, P., Pershina, V. & Raeder, S. & 9 others, Rudolph, D., Runke, J., Sarmiento, L. G., Schausten, B., Scherer, U., Thörle-Pospiech, P., Trautmann, N., Wegrzecki, M. & Wieczorek, P., 2024 Sept 23, In: Frontiers in Chemistry. 12, 13 p., 1474820.
Research output: Contribution to journal › Article › peer-review

Open Access
Spectroscopy along flerovium decay chains. II. Fine structure in odd-A ²⁸⁹Fl
Cox, D. M., Såmark-Roth, A., Rudolph, D., Sarmiento, L. G., Clark, R. M., Egido, J. L., Golubev, P., Heery, J., Yakushev, A., Åberg, S., Albers, H. M., Albertsson, M., Block, M., Brand, H., Calverley, T., Cantemir, R., Carlsson, B. G., Düllmann, C. E., Eberth, J. & Fahlander, C. & 34 others, Forsberg, U., Gates, J. M., Giacoppo, F., Götz, M., Götz, S., Herzberg, R.-D., Hrabar, Y., Jäger, E., Judson, D., Khuyagbaatar, J., Kindler, B., Kojouharov, I., Kratz, J. V., Krier, J., Kurz, N., Lens, L., Ljungberg, J., Lommel, B., Louko, J., Meyer, C.-C., Mistry, A., Mokry, C., Papadakis, P., Parr, E., Pore, J. L., Ragnarsson, I., Runke, J., Schädel, M., Schaffner, H., Schausten, B., Shaughnessy, D. A., Thörle-Pospiech, P., Trautmann, N. & Uusitalo, J., 2023 Feb 6, In: Physical Review C. 107, 2, 6 p., L021301.
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Spectroscopy along flerovium decay chains. III. Details on experiment, analysis, ²⁸²Cn, and spontaneous fission branches
Såmark-Roth, A., Cox, D. M., Rudolph, D., Sarmiento, L. G., Albertsson, M., Carlsson, B. G., Egido, J. L., Golubev, P., Heery, J., Yakushev, A., Åberg, S., Albers, H. M., Block, M., Brand, H., Calverley, T., Cantemir, R., Clark, R. M., Düllmann, C. E., Eberth, J. & Fahlander, C. & 34 others, Forsberg, U., Gates, J. M., Giacoppo, F., Götz, M., Götz, S., Herzberg, R.-D., Hrabar, Y., Jäger, E., Judson, D., Khuyagbaatar, J., Kindler, B., Kojouharov, I., Kratz, J. V., Krier, J., Kurz, N., Lens, L., Ljungberg, J., Lommel, B., Louko, J., Meyer, C.-C., Mistry, A., Mokry, C., Papadakis, P., Parr, E., Pore, J. L., Ragnarsson, I., Runke, J., Schädel, M., Schaffner, H., Schausten, B., Shaughnessy, D. A., Thörle-Pospiech, P., Trautmann, N. & Uusitalo, J., 2023 Feb 6, In: Physical Review C. 107, 2, 12 p., 024301.
Research output: Contribution to journal › Article › peer-review

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1 Active

Nuclear Structure at the Limits: Isotope-selective Spectroscopy
Rudolph, D. (PI), Fahlander, C. (CoI), Golubev, P. (CoI), Sarmiento Pico, L. (CoI), Cox, D. (Researcher), Hrabar, Y. (Research student), Såmark-Roth, A. (Research student), Forsberg, U. (Researcher), Lorenz, C. (Research student), Lalovic, N. (Researcher), Lalovic, N. (Research student), Forsberg, U. (Research student), Gellanki, J. (Research student), Hoischen, R. (Research student), Johansson, E. (Research student), Andersson, L.-L. (Research student), du Rietz, R. (Research student), Ekman, J. (Research student) & Andreoiu, C. (Research student)
Swedish Research Council
2002/01/01 → 2027/12/31
Project: Research

Cite this

Yakushev, A., Gates, J. M., Türler, A., Schädel, M., Düllmann, C. E., Ackermann, D., Andersson, L.-L., Block, M., Brüchle, W., Dvorak, J., Eberhardt, K., Essel, H. G., Even, J., Forsberg, U., Gorshkov, A., Graeger, R., Gregorich, K. E., Hartmann, W., Herzberg, R.-D., ... Wiehl, N. (2014). Superheavy Element Flerovium (Element 114) Is a Volatile Metal. Inorganic Chemistry, 53(3), 1624-1629. https://doi.org/10.1021/ic4026766

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abstract = "The electronic structure of superheavy elements (Z ≥ 104) and their chemical properties are dominated by relativistic effects. Recently two superheavy elements were recognized by the IUPAC and named flerovium (Fl, Z = 114) and livermorium (Lv, Z = 116). Fl is the heaviest element with which chemical experiments were performed. Here, we report on experiments that help answering the long-standing question whether Fl behaves rather like a noble gas or like a metal.",

keywords = "superheavy elements, element 114, gas chemistry",

author = "A. Yakushev and J.M. Gates and A. T{\"u}rler and M. Sch{\"a}del and C.E. D{\"u}llmann and D. Ackermann and L.-L. Andersson and M. Block and W. Br{\"u}chle and J. Dvorak and K. Eberhardt and H.G. Essel and J. Even and Ulrika Forsberg and A. Gorshkov and R. Graeger and K.E. Gregorich and W. Hartmann and R.-D. Herzberg and F.P. He{\ss}berger and D. Hild and A. H{\"u}bner and E. J{\"a}ger and J. Khuyagbaatar and B. Kindler and J.V. Kratz and J. Krier and N. Kurz and B. Lommel and L.J. Niewisch and H. Nitsche and J.P. Omtvedt and E. Parr and Z. Qin and Dirk Rudolph and J. Runke and B. Schausten and E. Schimpf and A. Semchenkov and J. Steiner and P. Th{\"o}rle-Pospiech and J. Uusitalo and M. Wegrzecki and N. Wiehl",

year = "2014",

doi = "10.1021/ic4026766",

language = "English",

volume = "53",

pages = "1624--1629",

journal = "Inorganic Chemistry",

issn = "1520-510X",

publisher = "The American Chemical Society (ACS)",

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Yakushev, A, Gates, JM, Türler, A, Schädel, M, Düllmann, CE, Ackermann, D, Andersson, L-L, Block, M, Brüchle, W, Dvorak, J, Eberhardt, K, Essel, HG, Even, J, Forsberg, U, Gorshkov, A, Graeger, R, Gregorich, KE, Hartmann, W, Herzberg, R-D, Heßberger, FP, Hild, D, Hübner, A, Jäger, E, Khuyagbaatar, J, Kindler, B, Kratz, JV, Krier, J, Kurz, N, Lommel, B, Niewisch, LJ, Nitsche, H, Omtvedt, JP, Parr, E, Qin, Z, Rudolph, D, Runke, J, Schausten, B, Schimpf, E, Semchenkov, A, Steiner, J, Thörle-Pospiech, P, Uusitalo, J, Wegrzecki, M & Wiehl, N 2014, 'Superheavy Element Flerovium (Element 114) Is a Volatile Metal', Inorganic Chemistry, vol. 53, no. 3, pp. 1624-1629. https://doi.org/10.1021/ic4026766

TY - JOUR

T1 - Superheavy Element Flerovium (Element 114) Is a Volatile Metal

AU - Yakushev, A.

AU - Gates, J.M.

AU - Türler, A.

AU - Schädel, M.

AU - Düllmann, C.E.

AU - Ackermann, D.

AU - Andersson, L.-L.

AU - Block, M.

AU - Brüchle, W.

AU - Dvorak, J.

AU - Eberhardt, K.

AU - Essel, H.G.

AU - Even, J.

AU - Forsberg, Ulrika

AU - Gorshkov, A.

AU - Graeger, R.

AU - Gregorich, K.E.

AU - Hartmann, W.

AU - Herzberg, R.-D.

AU - Heßberger, F.P.

AU - Hild, D.

AU - Hübner, A.

AU - Jäger, E.

AU - Khuyagbaatar, J.

AU - Kindler, B.

AU - Kratz, J.V.

AU - Krier, J.

AU - Kurz, N.

AU - Lommel, B.

AU - Niewisch, L.J.

AU - Nitsche, H.

AU - Omtvedt, J.P.

AU - Parr, E.

AU - Qin, Z.

AU - Rudolph, Dirk

AU - Runke, J.

AU - Schausten, B.

AU - Schimpf, E.

AU - Semchenkov, A.

AU - Steiner, J.

AU - Thörle-Pospiech, P.

AU - Uusitalo, J.

AU - Wegrzecki, M.

AU - Wiehl, N.

PY - 2014

Y1 - 2014

N2 - The electronic structure of superheavy elements (Z ≥ 104) and their chemical properties are dominated by relativistic effects. Recently two superheavy elements were recognized by the IUPAC and named flerovium (Fl, Z = 114) and livermorium (Lv, Z = 116). Fl is the heaviest element with which chemical experiments were performed. Here, we report on experiments that help answering the long-standing question whether Fl behaves rather like a noble gas or like a metal.

AB - The electronic structure of superheavy elements (Z ≥ 104) and their chemical properties are dominated by relativistic effects. Recently two superheavy elements were recognized by the IUPAC and named flerovium (Fl, Z = 114) and livermorium (Lv, Z = 116). Fl is the heaviest element with which chemical experiments were performed. Here, we report on experiments that help answering the long-standing question whether Fl behaves rather like a noble gas or like a metal.

KW - superheavy elements

KW - element 114

KW - gas chemistry

U2 - 10.1021/ic4026766

DO - 10.1021/ic4026766

M3 - Article

SN - 1520-510X

VL - 53

SP - 1624

EP - 1629

JO - Inorganic Chemistry

JF - Inorganic Chemistry

IS - 3

ER -

Superheavy Element Flerovium (Element 114) Is a Volatile Metal

Abstract

Subject classification (UKÄ)

Free keywords

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Research output

Manifestation of relativistic effects in the chemical properties of nihonium and moscovium revealed by gas chromatography studies

Spectroscopy along flerovium decay chains. II. Fine structure in odd-A 289Fl

Spectroscopy along flerovium decay chains. III. Details on experiment, analysis, 282Cn, and spontaneous fission branches

Projects

Nuclear Structure at the Limits: Isotope-selective Spectroscopy

Cite this

Spectroscopy along flerovium decay chains. II. Fine structure in odd-A ²⁸⁹Fl

Spectroscopy along flerovium decay chains. III. Details on experiment, analysis, ²⁸²Cn, and spontaneous fission branches