Synthesis and crystal structure of Ca2Ag1.83Al 0-67Ge1-50 - A solid solution with the NbCoB-type structure

Simeon Ponou; Sven Lidin

doi:10.1002/zaac.200900156

Synthesis and crystal structure of Ca₂Ag^1.83Al _0-67Ge_1-50 - A solid solution with the NbCoB-type structure

Simeon Ponou, Sven Lidin

Stockholm University

Research output: Contribution to journal › Article › peer-review

Abstract

The crystal structure of the new phase, Ca₂Ag _1.83Al_0.67Ge_1.50(1) (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) Â, b = 4.3807(2) Å c = 7.2211(3) Å, V= 648.65 Å³ (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg₂ (or CeCu₂) and Fe₂P type structures.

Original language	English
Pages (from-to)	2143-2146
Number of pages	4
Journal	Zeitschrift fur Anorganische und Allgemeine Chemie
Volume	635
Issue number	13-14
DOIs	https://doi.org/10.1002/zaac.200900156
Publication status	Published - 2009 Nov 1
Externally published	Yes

Free keywords

Intergrowth structure
Intermetallic phases
Silver
Solid solution
X-ray diffraction

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10.1002/zaac.200900156

Cite this

@article{35bd7df502254718bdae0a6f0433d9f8,

title = "Synthesis and crystal structure of Ca2Ag1.83Al 0-67Ge1-50 - A solid solution with the NbCoB-type structure",

abstract = "The crystal structure of the new phase, Ca2Ag 1.83Al0.67Ge1.50(1) (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) {\^A}, b = 4.3807(2) {\AA} c = 7.2211(3) {\AA}, V= 648.65 {\AA}3 (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg2 (or CeCu2) and Fe2P type structures.",

keywords = "Intergrowth structure, Intermetallic phases, Silver, Solid solution, X-ray diffraction",

author = "Simeon Ponou and Sven Lidin",

year = "2009",

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doi = "10.1002/zaac.200900156",

language = "English",

volume = "635",

pages = "2143--2146",

journal = "Zeitschrift fur Anorganische und Allgemeine Chemie",

issn = "0044-2313",

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TY - JOUR

T1 - Synthesis and crystal structure of Ca2Ag1.83Al 0-67Ge1-50 - A solid solution with the NbCoB-type structure

AU - Ponou, Simeon

AU - Lidin, Sven

PY - 2009/11/1

Y1 - 2009/11/1

N2 - The crystal structure of the new phase, Ca2Ag 1.83Al0.67Ge1.50(1) (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) Â, b = 4.3807(2) Å c = 7.2211(3) Å, V= 648.65 Å3 (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg2 (or CeCu2) and Fe2P type structures.

AB - The crystal structure of the new phase, Ca2Ag 1.83Al0.67Ge1.50(1) (1) was determined by single-crystal X-ray diffraction, after the compound was obtained by high temperature synthesis technique. 1 crystallizes with the NbCoB type structure in the orthorhombic space group Pmmn (no. 59) with unit cell parameters: a = 20.505(1) Â, b = 4.3807(2) Å c = 7.2211(3) Å, V= 648.65 Å3 (Z = 5). The structure of the title compound represent a rare intergrowth of the well known KHg2 (or CeCu2) and Fe2P type structures.

KW - Intergrowth structure

KW - Intermetallic phases

KW - Silver

KW - Solid solution

KW - X-ray diffraction

U2 - 10.1002/zaac.200900156

DO - 10.1002/zaac.200900156

M3 - Article

AN - SCOPUS:70449568342

SN - 0044-2313

VL - 635

SP - 2143

EP - 2146

JO - Zeitschrift fur Anorganische und Allgemeine Chemie

JF - Zeitschrift fur Anorganische und Allgemeine Chemie

IS - 13-14