Abstract
A convenient method for the synthesis and isolation of highly reactive formylsilanes by oxidative cleavage of α-silyl glycols is presented. The mild conditions provide an entry to acid- and heat-sensitive members of this theoretically intriguing class of compounds. The utility of the method is demonstrated through the isolation and subsequent diastereoselective derivatization of t-BuMe2- and t-BuPh2-formylsilanes, previously not reported in isolated form.
Original language | English |
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Pages (from-to) | 12268-12273 |
Journal | Journal of Organic Chemistry |
Volume | 78 |
Issue number | 23 |
DOIs | |
Publication status | Published - 2013 |
Subject classification (UKÄ)
- Chemical Sciences