Synthesis of (-)-pregaliellalactone, conversion of (-)-pregaliellalactone to (-)-galiellalactone by mycelia of Galiella rufa

Martin H Johansson; B Kopcke; H Anke; Olov Sterner

doi:10.1016/S0040-4020(02)00134-5

Synthesis of (-)-pregaliellalactone, conversion of (-)-pregaliellalactone to (-)-galiellalactone by mycelia of Galiella rufa

Martin H Johansson, B Kopcke, H Anke, Olov Sterner

Centre for Analysis and Synthesis

Research output: Contribution to journal › Article › peer-review

Abstract

An enantioselective synthesis of (-)-pregaliellalactone (1), a biosynthetic precursor of the potent fungal metabolite ( -)-galiellalactone (3) produced by several ascomycetes, is reported. When fed to a culture of Galiella rufa, 1 was efficiently converted to 3. (C) 2002 Elsevier Science Ltd. All rights reserved.

Original language	English
Pages (from-to)	2523-2528
Journal	Tetrahedron
Volume	58
Issue number	13
DOIs	https://doi.org/10.1016/S0040-4020(02)00134-5
Publication status	Published - 2002

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

Subject classification (UKÄ)

Organic Chemistry

Free keywords

pregaliellalactone
stannylation
Diels-Alder cyclisation
Galiella rufa
galiellalactone

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10.1016/S0040-4020(02)00134-5

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title = "Synthesis of (-)-pregaliellalactone, conversion of (-)-pregaliellalactone to (-)-galiellalactone by mycelia of Galiella rufa",

abstract = "An enantioselective synthesis of (-)-pregaliellalactone (1), a biosynthetic precursor of the potent fungal metabolite ( -)-galiellalactone (3) produced by several ascomycetes, is reported. When fed to a culture of Galiella rufa, 1 was efficiently converted to 3. (C) 2002 Elsevier Science Ltd. All rights reserved.",

keywords = "pregaliellalactone, stannylation, Diels-Alder cyclisation, Galiella rufa, galiellalactone",

author = "Johansson, {Martin H} and B Kopcke and H Anke and Olov Sterner",

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language = "English",

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T1 - Synthesis of (-)-pregaliellalactone, conversion of (-)-pregaliellalactone to (-)-galiellalactone by mycelia of Galiella rufa

AU - Johansson, Martin H

AU - Kopcke, B

AU - Anke, H

AU - Sterner, Olov

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Organic chemistry (S/LTH) (011001240)

PY - 2002

Y1 - 2002

N2 - An enantioselective synthesis of (-)-pregaliellalactone (1), a biosynthetic precursor of the potent fungal metabolite ( -)-galiellalactone (3) produced by several ascomycetes, is reported. When fed to a culture of Galiella rufa, 1 was efficiently converted to 3. (C) 2002 Elsevier Science Ltd. All rights reserved.

AB - An enantioselective synthesis of (-)-pregaliellalactone (1), a biosynthetic precursor of the potent fungal metabolite ( -)-galiellalactone (3) produced by several ascomycetes, is reported. When fed to a culture of Galiella rufa, 1 was efficiently converted to 3. (C) 2002 Elsevier Science Ltd. All rights reserved.

KW - pregaliellalactone

KW - stannylation

KW - Diels-Alder cyclisation

KW - Galiella rufa

KW - galiellalactone

U2 - 10.1016/S0040-4020(02)00134-5

DO - 10.1016/S0040-4020(02)00134-5

M3 - Article

SN - 0040-4020

VL - 58

SP - 2523

EP - 2528

JO - Tetrahedron

JF - Tetrahedron

IS - 13

ER -

Synthesis of (-)-pregaliellalactone, conversion of (-)-pregaliellalactone to (-)-galiellalactone by mycelia of Galiella rufa

Abstract

Bibliographical note

Subject classification (UKÄ)

Free keywords

Access to Document

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Cite this