Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid)

George E. Kostakis; Ebbe Nordlander; Athanassios C. Tsipis; Matti Haukka; John C. Plakatouras

doi:10.1016/j.inoche.2010.09.038

Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid)

George E. Kostakis, Ebbe Nordlander, Athanassios C. Tsipis, Matti Haukka, John C. Plakatouras

Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.

Original language	English
Pages (from-to)	87-91
Journal	Inorganic Chemistry Communications
Volume	14
Issue number	1
DOIs	https://doi.org/10.1016/j.inoche.2010.09.038
Publication status	Published - 2011

Bibliographical note

The information about affiliations in this record was updated in December 2015.
The record was previously connected to the following departments: Chemical Physics (S) (011001060)

Subject classification (UKÄ)

Atom and Molecular Physics and Optics

Free keywords

Hexameric water cluster
Zinc(II)
3D metal-supramolecular
architecture
H-bond
Crystal structure

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10.1016/j.inoche.2010.09.038

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title = "Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of \{[Zn(HL)(phen)(H2O)]center dot 3(H2O)\}2 (H3L = trans-aconitic acid)",

abstract = "The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit \{[Zn(HL)(phen)(H2O)]center dot 3(H2O)\}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.",

keywords = "Hexameric water cluster, Zinc(II), 3D metal-supramolecular, architecture, H-bond, Crystal structure",

author = "Kostakis, \{George E.\} and Ebbe Nordlander and Tsipis, \{Athanassios C.\} and Matti Haukka and Plakatouras, \{John C.\}",

note = "The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)",

year = "2011",

doi = "10.1016/j.inoche.2010.09.038",

language = "English",

volume = "14",

pages = "87--91",

journal = "Inorganic Chemistry Communications",

issn = "1879-0259",

publisher = "Elsevier",

number = "1",

}

Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid). / Kostakis, George E.; Nordlander, Ebbe; Tsipis, Athanassios C. et al.
In: Inorganic Chemistry Communications, Vol. 14, No. 1, 2011, p. 87-91.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid)

AU - Kostakis, George E.

AU - Nordlander, Ebbe

AU - Tsipis, Athanassios C.

AU - Haukka, Matti

AU - Plakatouras, John C.

N1 - The information about affiliations in this record was updated in December 2015. The record was previously connected to the following departments: Chemical Physics (S) (011001060)

PY - 2011

Y1 - 2011

N2 - The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.

AB - The reaction of Zn(NO3)(2)center dot 3(H2O) with trans-aconitic acid (H3L), in presence of chelating 1,10-phenanthroline, leads to the formation of a dinuclear unit {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}(2). The lattice water molecules are assembled as a centrosymmetric hexamer. The crystal structure, thermal studies, theoretical calculations, and the factors that stabilize this water hexamer are presented. (C) 2010 Elsevier B.V. All rights reserved.

KW - Hexameric water cluster

KW - Zinc(II)

KW - 3D metal-supramolecular

KW - architecture

KW - H-bond

KW - Crystal structure

UR - https://www.scopus.com/pages/publications/78651266797

U2 - 10.1016/j.inoche.2010.09.038

DO - 10.1016/j.inoche.2010.09.038

M3 - Article

SN - 1879-0259

VL - 14

SP - 87

EP - 91

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 1

ER -

Synthesis, structural and theoretical studies of a rare hexameric water cluster held in the lattice of {[Zn(HL)(phen)(H2O)]center dot 3(H2O)}2 (H3L = trans-aconitic acid)

Abstract

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Free keywords

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